Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation

Qianyan Zhang; Katsuaki Kawasumi; Yasutomo Segawa; Kenichiro Itami; Lawrence T. Scott

doi:10.1021/ja306992k

Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation

Qianyan Zhang, Katsuaki Kawasumi, Yasutomo Segawa, Kenichiro Itami, Lawrence T. Scott

Research Core for Interdisciplinary Sciences

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66 Citations (Scopus)

Abstract

All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

Original language	English
Pages (from-to)	15664-15667
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	38
DOIs	https://doi.org/10.1021/ja306992k
Publication status	Published - Sep 26 2012

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja306992k

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Zhang, Q., Kawasumi, K., Segawa, Y., Itami, K., & Scott, L. T. (2012). Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation. Journal of the American Chemical Society, 134(38), 15664-15667. https://doi.org/10.1021/ja306992k

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AU - Scott, Lawrence T.

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