Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation

Qianyan Zhang; Katsuaki Kawasumi; Yasutomo Segawa; Kenichiro Itami; Lawrence T. Scott

doi:10.1021/ja306992k

Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation

Qianyan Zhang, Katsuaki Kawasumi, Yasutomo Segawa, Kenichiro Itami, Lawrence T. Scott

Research Core for Interdisciplinary Sciences

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Abstract

All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

Original language	English
Pages (from-to)	15664-15667
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	38
DOIs	https://doi.org/10.1021/ja306992k
Publication status	Published - Sep 26 2012

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja306992k

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title = "Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation",

abstract = "All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.",

author = "Qianyan Zhang and Katsuaki Kawasumi and Yasutomo Segawa and Kenichiro Itami and Scott, {Lawrence T.}",

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AU - Zhang, Qianyan

AU - Kawasumi, Katsuaki

AU - Segawa, Yasutomo

AU - Itami, Kenichiro

AU - Scott, Lawrence T.

PY - 2012/9/26

Y1 - 2012/9/26

N2 - All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

AB - All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

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Palladium-catalyzed C-H activation taken to the limit. Flattening an aromatic bowl by total arylation

Abstract

ASJC Scopus subject areas

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