Palladium-catalyzed allylation reaction of alkynylborates

Naoki Ishida, Tatsuo Shinmoto, Shota Sawano, Tomoya Miura, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Alkynyl(aryl)(diorganyl)borates, anionic tetrahedral boron compounds, reacted with allylic bromides in the presence of a palladium(0) catalyst to produce (diorganyl)(trisubstituted alkenyl)boranes. Allylation took place at the alkynyl carbon β to boron, inducing 1,2-migration of the aryl group on the anionic boron center to the α-carbon.

Original languageEnglish
Pages (from-to)1380-1385
Number of pages6
JournalBulletin of the Chemical Society of Japan
Volume83
Issue number11
DOIs
Publication statusPublished - 2010
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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