Abstract
Oxidative addition of a hypervalent organosulfur compound, 1,5-dithioniabicyclo[3.3.0]octane bis(trifluoromethanesulfonate) (1), to diene complexes of zirconium and tantalum, Cp2Zr(η4-1,3-butadiene) and CpTa(η4-1,3-butadiene)2, in THF resulted in the almost quantitative formation of bis(triflate) complexes of zirconium, Cp2Zr(OTf)2(thf) (3), and tantalum, CpTa(η4-1,3-butadiene)(OTf)2 (5), respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 793-794 |
| Number of pages | 2 |
| Journal | Chemistry Letters |
| Issue number | 8 |
| Publication status | Published - 1997 |
| Externally published | Yes |
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Cite this
Oxidative reaction of 1,5-dithioniabicyclo[3.3.0]octane bis(trifluoromethanesulfonate) with diene complexes of zirconium and tantalum : Synthesis of Cp2Zr(OTf)2(thf) and Cp(η4-1,3-butadiene)Ta(OTf)2. / Mashima, Kazushi; Oshiki, Toshiyuki; Matsuo, Yutaka; Tani, Kazuhide.
In: Chemistry Letters, No. 8, 1997, p. 793-794.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Oxidative reaction of 1,5-dithioniabicyclo[3.3.0]octane bis(trifluoromethanesulfonate) with diene complexes of zirconium and tantalum
T2 - Synthesis of Cp2Zr(OTf)2(thf) and Cp(η4-1,3-butadiene)Ta(OTf)2
AU - Mashima, Kazushi
AU - Oshiki, Toshiyuki
AU - Matsuo, Yutaka
AU - Tani, Kazuhide
PY - 1997
Y1 - 1997
N2 - Oxidative addition of a hypervalent organosulfur compound, 1,5-dithioniabicyclo[3.3.0]octane bis(trifluoromethanesulfonate) (1), to diene complexes of zirconium and tantalum, Cp2Zr(η4-1,3-butadiene) and CpTa(η4-1,3-butadiene)2, in THF resulted in the almost quantitative formation of bis(triflate) complexes of zirconium, Cp2Zr(OTf)2(thf) (3), and tantalum, CpTa(η4-1,3-butadiene)(OTf)2 (5), respectively.
AB - Oxidative addition of a hypervalent organosulfur compound, 1,5-dithioniabicyclo[3.3.0]octane bis(trifluoromethanesulfonate) (1), to diene complexes of zirconium and tantalum, Cp2Zr(η4-1,3-butadiene) and CpTa(η4-1,3-butadiene)2, in THF resulted in the almost quantitative formation of bis(triflate) complexes of zirconium, Cp2Zr(OTf)2(thf) (3), and tantalum, CpTa(η4-1,3-butadiene)(OTf)2 (5), respectively.
UR - http://www.scopus.com/inward/record.url?scp=0012625917&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0012625917&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0012625917
SP - 793
EP - 794
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 8
ER -