Oxidative generation of diarylcarbenium ion pools

Masayuki Okajima, Kazuya Soga, Toshiki Nokami, Seiji Suga, Jun Ichi Yoshida

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

(Figure Presented) "Cation pools" of diarylcarbenium ions have been generated by the oxidative C-H bond dissociation of diarylmethanes using anodic oxidation. "Diarylcarbenium ion pools" thus generated react with various nucleophiles, such as allylsilanes, ketene silyl acetals, and aromatic compounds. The reductive homocoupling of the "diarylcarbenium ion pool" has been achieved. The dimer thus obtained also serves as a precursor of the "diarylcarbenium ion pool" via oxidative C-C bond dissociation.

Original languageEnglish
Pages (from-to)5005-5007
Number of pages3
JournalOrganic Letters
Volume8
Issue number22
DOIs
Publication statusPublished - Oct 26 2006
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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  • Cite this

    Okajima, M., Soga, K., Nokami, T., Suga, S., & Yoshida, J. I. (2006). Oxidative generation of diarylcarbenium ion pools. Organic Letters, 8(22), 5005-5007. https://doi.org/10.1021/ol061647c