Oxidative desulfurization-fluorination of alkanol xanthates. Control of the reaction pathway to fluorination or trifluoromethoxylation

Kiyoshi Kanie, Yoichiro Tanaka, Masaki Shimizu, Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The reagent consisting of 70% HF-py (py = pyridine) and a halonium oxidant converts R-OCS2Me into either R-OCF3 (R = primary) or R-F (R = secondary, tertiary or benzylic) whereas the 50% HF-py system converts R-OCS2Me (R = secondary) into R-OCF3.

Original languageEnglish
Pages (from-to)309-310
Number of pages2
JournalChemical Communications
Issue number3
Publication statusPublished - 1997

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Fluorination
Desulfurization
Oxidants
Pyridine
pyridine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Oxidative desulfurization-fluorination of alkanol xanthates. Control of the reaction pathway to fluorination or trifluoromethoxylation. / Kanie, Kiyoshi; Tanaka, Yoichiro; Shimizu, Masaki; Kuroboshi, Manabu; Hiyama, Tamejiro.

In: Chemical Communications, No. 3, 1997, p. 309-310.

Research output: Contribution to journalArticle

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AU - Kuroboshi, Manabu

AU - Hiyama, Tamejiro

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