Oxidative desulfurization-fluorination of alkanol xanthates. Control of the reaction pathway to fluorination or trifluoromethoxylation

Kiyoshi Kanie, Yoichiro Tanaka, Masaki Shimizu, Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

The reagent consisting of 70% HF-py (py = pyridine) and a halonium oxidant converts R-OCS2Me into either R-OCF3 (R = primary) or R-F (R = secondary, tertiary or benzylic) whereas the 50% HF-py system converts R-OCS2Me (R = secondary) into R-OCF3.

Original languageEnglish
Pages (from-to)309-310
Number of pages2
JournalChemical Communications
Issue number3
DOIs
Publication statusPublished - Jan 1 1997

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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