Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement

Manabu Kuroboshi, Satoru Furuta, Tamejiro Hiyama

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.

Original languageEnglish
Pages (from-to)6121-6122
Number of pages2
JournalTetrahedron Letters
Volume36
Issue number34
DOIs
Publication statusPublished - Aug 21 1995
Externally publishedYes

Fingerprint

Fluorination
Halogenation
Desulfurization
Ethanol
Oxidation
Substrates
1,3-dibromo-5,5-dimethylhydantoin
methylthioethanol

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement. / Kuroboshi, Manabu; Furuta, Satoru; Hiyama, Tamejiro.

In: Tetrahedron Letters, Vol. 36, No. 34, 21.08.1995, p. 6121-6122.

Research output: Contribution to journalArticle

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abstract = "Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.",
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