Oxidative desulfurization-fluorination of 1-substituted 2,2,2-tris(methylthio)ethanol induces difluorination under oxidation or rearrangement

Manabu Kuroboshi, Satoru Furuta, Tamejiro Hiyama

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.

Original languageEnglish
Pages (from-to)6121-6122
Number of pages2
JournalTetrahedron Letters
Volume36
Issue number34
DOIs
Publication statusPublished - Aug 21 1995
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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