Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp): Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4

Takayoshi Suzuki; Naoki Tsuji; Kazuo Kashiwabara; Kazuyuki Tatsumi

doi:10.1021/ic000289l

Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp): Crystal structures and spectroscopic properties of [Co(s₂O)(dmpp)₂]PF₆ and [Co(Se₂)(dmpp)₂]BF₄

Takayoshi Suzuki, Naoki Tsuji, Kazuo Kashiwabara, Kazuyuki Tatsumi

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

[Co(S₂O-κ²S and Se₂)(dmpp)₂]⁺ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S₂O^2- and Se₂^2- moietes. The analogous [Co(S₂O-κ²S(depe)₂]⁺ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se₂)(dmpe)₂]⁺ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.

Original language	English
Pages (from-to)	3938-3941
Number of pages	4
Journal	Inorganic Chemistry
Volume	39
Issue number	17
DOIs	https://doi.org/10.1021/ic000289l
Publication status	Published - Aug 21 2000
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp) : Crystal structures and spectroscopic properties of [Co(s₂O)(dmpp)₂]PF₆ and [Co(Se₂)(dmpp)₂]BF₄. / Suzuki, Takayoshi; Tsuji, Naoki; Kashiwabara, Kazuo et al.

In: Inorganic Chemistry, Vol. 39, No. 17, 21.08.2000, p. 3938-3941.

Research output: Contribution to journal › Article › peer-review

Suzuki, T, Tsuji, N, Kashiwabara, K & Tatsumi, K 2000, 'Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp): Crystal structures and spectroscopic properties of [Co(s₂O)(dmpp)₂]PF₆ and [Co(Se₂)(dmpp)₂]BF₄', Inorganic Chemistry, vol. 39, no. 17, pp. 3938-3941. https://doi.org/10.1021/ic000289l

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abstract = "[Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.",

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