Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp): Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4

Takayoshi Suzuki, Naoki Tsuji, Kazuo Kashiwabara, Kazuyuki Tatsumi

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5 Citations (Scopus)

Abstract

[Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.

Original languageEnglish
Pages (from-to)3938-3941
Number of pages4
JournalInorganic Chemistry
Volume39
Issue number17
DOIs
Publication statusPublished - Aug 21 2000
Externally publishedYes

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Propane
Ethane
Cobalt
propane
ethane
cobalt
Crystal structure
crystal structure
X rays
x rays

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

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title = "Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp): Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4",
abstract = "[Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.",
author = "Takayoshi Suzuki and Naoki Tsuji and Kazuo Kashiwabara and Kazuyuki Tatsumi",
year = "2000",
month = "8",
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doi = "10.1021/ic000289l",
language = "English",
volume = "39",
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TY - JOUR

T1 - Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp)

T2 - Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4

AU - Suzuki, Takayoshi

AU - Tsuji, Naoki

AU - Kashiwabara, Kazuo

AU - Tatsumi, Kazuyuki

PY - 2000/8/21

Y1 - 2000/8/21

N2 - [Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.

AB - [Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.

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