Abstract
[Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.
| Original language | English |
|---|---|
| Pages (from-to) | 3938-3941 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry |
| Volume | 39 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - Aug 21 2000 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Suzuki, T., Tsuji, N., Kashiwabara, K., & Tatsumi, K. (2000). Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp): Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4. Inorganic Chemistry, 39(17), 3938-3941. https://doi.org/10.1021/ic000289l