Abstract
[Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.
| Original language | English |
|---|---|
| Pages (from-to) | 3938-3941 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry |
| Volume | 39 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - Aug 21 2000 |
| Externally published | Yes |
Fingerprint
ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp) : Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4. / Suzuki, Takayoshi; Tsuji, Naoki; Kashiwabara, Kazuo; Tatsumi, Kazuyuki.
In: Inorganic Chemistry, Vol. 39, No. 17, 21.08.2000, p. 3938-3941.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Oxidative additions of cyclo-octasulfur and cyclo-octaselenium to the cobalt(II) complex of 1,3-bis(dimethylphosphino)propane (dmpp)
T2 - Crystal structures and spectroscopic properties of [Co(s2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4
AU - Suzuki, Takayoshi
AU - Tsuji, Naoki
AU - Kashiwabara, Kazuo
AU - Tatsumi, Kazuyuki
PY - 2000/8/21
Y1 - 2000/8/21
N2 - [Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.
AB - [Co(S2O-κ2S and Se2)(dmpp)2]+ complexes were prepared and characterized by X-ray analyses and UV - vis spectra to have side-on-bonded S2O2- and Se22- moietes. The analogous [Co(S2O-κ2S(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) and [Co(Se2)(dmpe)2]+ (dmpe = 1,2-bis(dimethylphosphino)ethane) complexes were also prepared.
UR - http://www.scopus.com/inward/record.url?scp=0034698598&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034698598&partnerID=8YFLogxK
U2 - 10.1021/ic000289l
DO - 10.1021/ic000289l
M3 - Article
C2 - 11196794
AN - SCOPUS:0034698598
VL - 39
SP - 3938
EP - 3941
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 17
ER -