Oxidation of aromatic and aliphatic aldehydes to carboxylic acids by Geotrichum candidum aldehyde dehydrogenase

Tomoyasu Hoshino; Emi Yamabe; Muhammad Arisyi Hawari; Mayumi Tamura; Shuji Kanamaru; Keisuke Yoshida; Afifa Ayu Koesoema; Tomoko Matsuda

doi:10.1016/j.tet.2020.131387

Oxidation of aromatic and aliphatic aldehydes to carboxylic acids by Geotrichum candidum aldehyde dehydrogenase

Tomoyasu Hoshino, Emi Yamabe, Muhammad Arisyi Hawari, Mayumi Tamura, Shuji Kanamaru, Keisuke Yoshida, Afifa Ayu Koesoema, Tomoko Matsuda

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Oxidation reaction is one of the most important and indispensable organic reactions, so that green and sustainable catalysts for oxidation are necessary to be developed. Herein, biocatalytic oxidation of aldehydes was investigated, resulted in the synthesis of both aromatic and aliphatic carboxylic acids using a Geotrichum candidum aldehyde dehydrogenase (GcALDH). Moreover, selective oxidation of dialdehydes to aldehydic acids by GcALDH was also successful.

Original language	English
Article number	131387
Journal	Tetrahedron
Volume	76
Issue number	33
DOIs	https://doi.org/10.1016/j.tet.2020.131387
Publication status	Published - Aug 14 2020
Externally published	Yes

Keywords

Aldehyde
Aldehyde dehydrogenase
Carboxylic acid
Enzyme
Green chemistry
Oxidation
Selectivity

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2020.131387

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title = "Oxidation of aromatic and aliphatic aldehydes to carboxylic acids by Geotrichum candidum aldehyde dehydrogenase",

abstract = "Oxidation reaction is one of the most important and indispensable organic reactions, so that green and sustainable catalysts for oxidation are necessary to be developed. Herein, biocatalytic oxidation of aldehydes was investigated, resulted in the synthesis of both aromatic and aliphatic carboxylic acids using a Geotrichum candidum aldehyde dehydrogenase (GcALDH). Moreover, selective oxidation of dialdehydes to aldehydic acids by GcALDH was also successful.",

keywords = "Aldehyde, Aldehyde dehydrogenase, Carboxylic acid, Enzyme, Green chemistry, Oxidation, Selectivity",

author = "Tomoyasu Hoshino and Emi Yamabe and Hawari, {Muhammad Arisyi} and Mayumi Tamura and Shuji Kanamaru and Keisuke Yoshida and Koesoema, {Afifa Ayu} and Tomoko Matsuda",

note = "Funding Information: This work was partially supported by the Japan Society for the Promotion of Science , Japan (grant number JP16K05864 and JP19K05560 ) to Tomoko Matsuda. Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd",

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doi = "10.1016/j.tet.2020.131387",

language = "English",

volume = "76",

journal = "Tetrahedron",

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T1 - Oxidation of aromatic and aliphatic aldehydes to carboxylic acids by Geotrichum candidum aldehyde dehydrogenase

AU - Hoshino, Tomoyasu

AU - Yamabe, Emi

AU - Hawari, Muhammad Arisyi

AU - Tamura, Mayumi

AU - Kanamaru, Shuji

AU - Yoshida, Keisuke

AU - Koesoema, Afifa Ayu

AU - Matsuda, Tomoko

N1 - Funding Information: This work was partially supported by the Japan Society for the Promotion of Science , Japan (grant number JP16K05864 and JP19K05560 ) to Tomoko Matsuda. Publisher Copyright: © 2020 Elsevier Ltd

PY - 2020/8/14

Y1 - 2020/8/14

N2 - Oxidation reaction is one of the most important and indispensable organic reactions, so that green and sustainable catalysts for oxidation are necessary to be developed. Herein, biocatalytic oxidation of aldehydes was investigated, resulted in the synthesis of both aromatic and aliphatic carboxylic acids using a Geotrichum candidum aldehyde dehydrogenase (GcALDH). Moreover, selective oxidation of dialdehydes to aldehydic acids by GcALDH was also successful.

AB - Oxidation reaction is one of the most important and indispensable organic reactions, so that green and sustainable catalysts for oxidation are necessary to be developed. Herein, biocatalytic oxidation of aldehydes was investigated, resulted in the synthesis of both aromatic and aliphatic carboxylic acids using a Geotrichum candidum aldehyde dehydrogenase (GcALDH). Moreover, selective oxidation of dialdehydes to aldehydic acids by GcALDH was also successful.

KW - Aldehyde

KW - Aldehyde dehydrogenase

KW - Carboxylic acid

KW - Enzyme

KW - Green chemistry

KW - Oxidation

KW - Selectivity

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JO - Tetrahedron

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ER -

Oxidation of aromatic and aliphatic aldehydes to carboxylic acids by Geotrichum candidum aldehyde dehydrogenase

Abstract

Keywords

ASJC Scopus subject areas

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