Organic metals involving double chain donor arrangements, (BMDT-TTF)2(R1R2-TCNQ) [R1 = H, Me, R2 = Cl, Br]

T. Mochida, T. Hasegawa, Ryusuke Kondo, S. Kagoshima, Y. Iwasa

Research output: Contribution to journalArticle

Abstract

Two-component charge-transfer complexes of (BEDT-TTF) (TCNQ) analogues were systematically investigated focusing on the functionality of acceptor molecules and the well-known 'side-by-side' S...S networks characteristic of BEDT-TTF-type donors. The title compounds were found to exhibit unique crystal structures involving double-column donor arrangements. The compounds also showed metallic conductivities accompanied by metal-insulator transitions at low temperatures.

Original languageEnglish
Pages (from-to)1680
Number of pages1
JournalSynthetic Metals
Volume102
Issue number1-3
DOIs
Publication statusPublished - Jun 1999
Externally publishedYes

Fingerprint

Metal insulator transition
Charge transfer
Crystal structure
Metals
Molecules
metals
charge transfer
insulators
analogs
conductivity
Temperature
crystal structure
molecules
BEDT-TTF
tetracyanoquinodimethane

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Organic metals involving double chain donor arrangements, (BMDT-TTF)2(R1R2-TCNQ) [R1 = H, Me, R2 = Cl, Br]. / Mochida, T.; Hasegawa, T.; Kondo, Ryusuke; Kagoshima, S.; Iwasa, Y.

In: Synthetic Metals, Vol. 102, No. 1-3, 06.1999, p. 1680.

Research output: Contribution to journalArticle

Mochida, T. ; Hasegawa, T. ; Kondo, Ryusuke ; Kagoshima, S. ; Iwasa, Y. / Organic metals involving double chain donor arrangements, (BMDT-TTF)2(R1R2-TCNQ) [R1 = H, Me, R2 = Cl, Br]. In: Synthetic Metals. 1999 ; Vol. 102, No. 1-3. pp. 1680.
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