One-pot synthesis of poly(ionic liquid)s with 1,2,3-triazolium-based backbones: Via clickable ionic liquid monomers

Ruka Hirai, Tatsuki Hibino, Takaichi Watanabe, Takashi Teranishi, Tsutomu Ono

Research output: Contribution to journalArticlepeer-review

Abstract

Clickable α-azide-ω-alkyne ionic liquid monomers were developed and subsequently applied to the one-pot synthesis of ionically conducting poly(ionic liquid)s with 1,2,3-triazolium-based backbones through a click chemistry strategy. This approach does not require the use of solvents, polymerisation mediators, or catalysts. The obtained poly(ionic liquid)s were characterized by NMR, differential scanning calorimetry, thermogravimetric analysis, and impedance spectroscopy analysis. Moreover, these poly(ionic liquid)s were cross-linked via N-alkylation with a dianion quarternizing agent to achieve enhanced ionic conductivity and mechanical strength. The resulting free-standing films showed a Young's modulus up to 4.8 MPa and ionic conductivities up to 4.60 × 10-8 S cm-1 at 30 °C. This facile synthetic strategy has the potential to expand the availability of poly(ionic liquid)s and promote the development of functional materials.

Original languageEnglish
Pages (from-to)37743-37748
Number of pages6
JournalRSC Advances
Volume10
Issue number62
DOIs
Publication statusPublished - Oct 13 2020

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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