One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones

Takuzo Komiyama, Yutaka Takaguchi, Sadao Tsuboi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The base-catalyzed Diels-Alder reactions of 4-arylthio-3-hydroxy-2-pyrones are reported. Treatment of 4-arylthio-3-hydroxy-2-pyrones and dienophiles with triethylamine gave 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction involving a decarboxylation in excellent to reasonable yields.

Original languageEnglish
Pages (from-to)2131-2136
Number of pages6
JournalSynthetic Communications
Volume37
Issue number13
DOIs
Publication statusPublished - Jan 2007

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Keywords

  • 2-arylthio-2-cyclohexenones
  • 3-hydroxy-2-pyrones
  • Decarboxylation
  • Diels-Alder reaction
  • One-pot reaction

ASJC Scopus subject areas

  • Organic Chemistry

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