One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

Tomoya Miura, Takamasa Tanaka, Tsuneaki Biyajima, Akira Yada, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

140 Citations (Scopus)

Abstract

Triple strike: Copper(I) and rhodium(II) complexes can cooperate to facilely convert terminal alkynes into α-allyl-α-amino ketones through triazole intermediates. This synthetic process achieves the regioselective multifunctionalization of terminal alkynes with the formation of C-C, C-O, and C-N bonds in one pot.

Original languageEnglish
Pages (from-to)3883-3886
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number14
DOIs
Publication statusPublished - Apr 2 2013
Externally publishedYes

Keywords

  • allylation
  • copper
  • rhodium
  • terminal alkynes
  • triazoles

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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