One dimensional hydrogen bonded arrangement in new Schiff-base compound (E)-2-(2,5-dimethoxybenzylideneamino)phenol (1): Synthesis, characterization, crystal structure and conformational studies

Aliakbar Dehno Khalaji, Hossein Mighani, Hamid Reza Bijanzadeh, Kazuma Gotoh, Hiroyuki Ishida

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

New Schiff-base compound (E)-2-(2,5-dimethoxybenzylideneamino)phenol (1) was synthesized and characterized by elemental analyses, FT-IR and 1H-NMR spectroscopy and single crystal X-ray diffraction. Molecular orbital calculation has been carried out for 1 by using HF method at 6-31G basis set. The title compound 1 crystallizes in monoclinic system, space group C2/c, with a = 19.4581(13) Å, b = 9.5805(5) Å, β = 93.471(2)°, V = 2575.9(3) Å3 and Z = 8. In the crystal structure two molecules are stabilized by a pair of intermolecular O1- H1•••N1i hydrogen bonds. The dimeric units are further linked via C6-H6•••O3ii hydrogen bond.

Original languageEnglish
Pages (from-to)1515-1519
Number of pages5
JournalJournal of Chemical Crystallography
Volume41
Issue number10
DOIs
Publication statusPublished - Oct 1 2011

Keywords

  • HF(6-31G)
  • Hydrogen bonds
  • One-dimensional
  • Schiff-base
  • Spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

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