Observation of π backbonding features appearing in Fe 2p X-ray absorption spectra and Fe 1s-4p-1s resonant X-ray emission spectra of RbMn[Fe(CN)6]

Yoshinori Kitajima, Yusuke Nanba, Masayuki Tanaka, Yuji Koga, Akihiro Ueno, Kosuke Nakagawa, Hiroko Tokoro, Shin Ichi Ohkoshi, Toshiaki Iwazumi, Kozo Okada, Yasuhito Isozumi

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1 Citation (Scopus)

Abstract

Satellite features by p backbonding (metal-to-ligand charge transfer) were observed in both Fe 2p (L3,2-edge) X-ray absorption spectra and 1s-4p-1s resonant X-ray emission spectra for RbMn[Fe(CN)6], which can be theoretically explained using common parameters. Fe L3,2-edge and Mn L3,2-edge X-ray absorption spectra for low temperature phase are also presented.

Original languageEnglish
Article number012082
JournalJournal of Physics: Conference Series
Volume430
Issue number1
DOIs
Publication statusPublished - 2013

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emission spectra
absorption spectra
x rays
charge transfer
ligands
metals

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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Observation of π backbonding features appearing in Fe 2p X-ray absorption spectra and Fe 1s-4p-1s resonant X-ray emission spectra of RbMn[Fe(CN)6]. / Kitajima, Yoshinori; Nanba, Yusuke; Tanaka, Masayuki; Koga, Yuji; Ueno, Akihiro; Nakagawa, Kosuke; Tokoro, Hiroko; Ohkoshi, Shin Ichi; Iwazumi, Toshiaki; Okada, Kozo; Isozumi, Yasuhito.

In: Journal of Physics: Conference Series, Vol. 430, No. 1, 012082, 2013.

Research output: Contribution to journalArticle

Kitajima, Yoshinori ; Nanba, Yusuke ; Tanaka, Masayuki ; Koga, Yuji ; Ueno, Akihiro ; Nakagawa, Kosuke ; Tokoro, Hiroko ; Ohkoshi, Shin Ichi ; Iwazumi, Toshiaki ; Okada, Kozo ; Isozumi, Yasuhito. / Observation of π backbonding features appearing in Fe 2p X-ray absorption spectra and Fe 1s-4p-1s resonant X-ray emission spectra of RbMn[Fe(CN)6]. In: Journal of Physics: Conference Series. 2013 ; Vol. 430, No. 1.
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abstract = "Satellite features by p backbonding (metal-to-ligand charge transfer) were observed in both Fe 2p (L3,2-edge) X-ray absorption spectra and 1s-4p-1s resonant X-ray emission spectra for RbMn[Fe(CN)6], which can be theoretically explained using common parameters. Fe L3,2-edge and Mn L3,2-edge X-ray absorption spectra for low temperature phase are also presented.",
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T1 - Observation of π backbonding features appearing in Fe 2p X-ray absorption spectra and Fe 1s-4p-1s resonant X-ray emission spectra of RbMn[Fe(CN)6]

AU - Kitajima, Yoshinori

AU - Nanba, Yusuke

AU - Tanaka, Masayuki

AU - Koga, Yuji

AU - Ueno, Akihiro

AU - Nakagawa, Kosuke

AU - Tokoro, Hiroko

AU - Ohkoshi, Shin Ichi

AU - Iwazumi, Toshiaki

AU - Okada, Kozo

AU - Isozumi, Yasuhito

PY - 2013

Y1 - 2013

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AB - Satellite features by p backbonding (metal-to-ligand charge transfer) were observed in both Fe 2p (L3,2-edge) X-ray absorption spectra and 1s-4p-1s resonant X-ray emission spectra for RbMn[Fe(CN)6], which can be theoretically explained using common parameters. Fe L3,2-edge and Mn L3,2-edge X-ray absorption spectra for low temperature phase are also presented.

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JF - Journal of Physics: Conference Series

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