Observation of π backbonding features appearing in Fe 2p X-ray absorption spectra and Fe 1s-4p-1s resonant X-ray emission spectra of RbMn[Fe(CN)6]

Yoshinori Kitajima, Yusuke Nanba, Masayuki Tanaka, Yuji Koga, Akihiro Ueno, Kosuke Nakagawa, Hiroko Tokoro, Shin Ichi Ohkoshi, Toshiaki Iwazumi, Kozo Okada, Yasuhito Isozumi

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Abstract

Satellite features by p backbonding (metal-to-ligand charge transfer) were observed in both Fe 2p (L3,2-edge) X-ray absorption spectra and 1s-4p-1s resonant X-ray emission spectra for RbMn[Fe(CN)6], which can be theoretically explained using common parameters. Fe L3,2-edge and Mn L3,2-edge X-ray absorption spectra for low temperature phase are also presented.

Original languageEnglish
Article number012082
JournalJournal of Physics: Conference Series
Volume430
Issue number1
DOIs
Publication statusPublished - 2013

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ASJC Scopus subject areas

  • Physics and Astronomy(all)

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