Abstract
The nucleophilic phosphine-catalyzed diastereoselective iodocyclization of linear isoprenoids bearing an oxygen terminal group was investigated. TBDMS ether of homogeraniol and TBDMS ester of homogeranic acid were successfully converted to the corresponding iodopolycyclic products in the presence of a catalytic amount of triphenylphosphine with complete diastereoselectivity.
| Original language | English |
|---|---|
| Pages (from-to) | 249-255 |
| Number of pages | 7 |
| Journal | Heterocycles |
| Volume | 82 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2010 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Analytical Chemistry
- Organic Chemistry
- Pharmacology
Cite this
Nucleophilic phosphine-catalyzed iodocyclization of isoprenoids bearing an oxygen terminal group. / Sakakura, Akira; Shomi, Gakujun; Ukai, Atsushi; Ishihara, Kazuaki.
In: Heterocycles, Vol. 82, No. 1, 2010, p. 249-255.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nucleophilic phosphine-catalyzed iodocyclization of isoprenoids bearing an oxygen terminal group
AU - Sakakura, Akira
AU - Shomi, Gakujun
AU - Ukai, Atsushi
AU - Ishihara, Kazuaki
PY - 2010
Y1 - 2010
N2 - The nucleophilic phosphine-catalyzed diastereoselective iodocyclization of linear isoprenoids bearing an oxygen terminal group was investigated. TBDMS ether of homogeraniol and TBDMS ester of homogeranic acid were successfully converted to the corresponding iodopolycyclic products in the presence of a catalytic amount of triphenylphosphine with complete diastereoselectivity.
AB - The nucleophilic phosphine-catalyzed diastereoselective iodocyclization of linear isoprenoids bearing an oxygen terminal group was investigated. TBDMS ether of homogeraniol and TBDMS ester of homogeranic acid were successfully converted to the corresponding iodopolycyclic products in the presence of a catalytic amount of triphenylphosphine with complete diastereoselectivity.
UR - http://www.scopus.com/inward/record.url?scp=79751507652&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79751507652&partnerID=8YFLogxK
U2 - 10.3987/COM-09-S(E)1
DO - 10.3987/COM-09-S(E)1
M3 - Article
AN - SCOPUS:79751507652
VL - 82
SP - 249
EP - 255
JO - Heterocycles
JF - Heterocycles
SN - 0385-5414
IS - 1
ER -