Novel photoreaction using diphenyl disulfide derivatives: Photoinduced oxidation of allyl alcohol

Takaaki Tsuboi; Yutaka Takaguchi; Sadao Tsuboi

doi:10.1246/bcsj.81.361

Novel photoreaction using diphenyl disulfide derivatives: Photoinduced oxidation of allyl alcohol

Takaaki Tsuboi, Yutaka Takaguchi, Sadao Tsuboi

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Allyl alcohols are oxidized to acrylaldehydes using diphenyl disulfide derivatives upon photoirradiation. The reaction occurs via α-hydrogen abstraction by a sulfanyl radical. Interestingly, the oxidation reaction occurs in moderate yield when a dendrimer disulfide is used as a mediator.

Original language	English
Pages (from-to)	361-368
Number of pages	8
Journal	Bulletin of the Chemical Society of Japan
Volume	81
Issue number	3
DOIs	https://doi.org/10.1246/bcsj.81.361
Publication status	Published - Dec 1 2008

ASJC Scopus subject areas

Chemistry(all)

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title = "Novel photoreaction using diphenyl disulfide derivatives: Photoinduced oxidation of allyl alcohol",

abstract = "Allyl alcohols are oxidized to acrylaldehydes using diphenyl disulfide derivatives upon photoirradiation. The reaction occurs via α-hydrogen abstraction by a sulfanyl radical. Interestingly, the oxidation reaction occurs in moderate yield when a dendrimer disulfide is used as a mediator.",

author = "Takaaki Tsuboi and Yutaka Takaguchi and Sadao Tsuboi",

year = "2008",

month = dec,

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doi = "10.1246/bcsj.81.361",

language = "English",

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T1 - Novel photoreaction using diphenyl disulfide derivatives

T2 - Photoinduced oxidation of allyl alcohol

AU - Tsuboi, Takaaki

AU - Takaguchi, Yutaka

AU - Tsuboi, Sadao

PY - 2008/12/1

Y1 - 2008/12/1

N2 - Allyl alcohols are oxidized to acrylaldehydes using diphenyl disulfide derivatives upon photoirradiation. The reaction occurs via α-hydrogen abstraction by a sulfanyl radical. Interestingly, the oxidation reaction occurs in moderate yield when a dendrimer disulfide is used as a mediator.

AB - Allyl alcohols are oxidized to acrylaldehydes using diphenyl disulfide derivatives upon photoirradiation. The reaction occurs via α-hydrogen abstraction by a sulfanyl radical. Interestingly, the oxidation reaction occurs in moderate yield when a dendrimer disulfide is used as a mediator.

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DO - 10.1246/bcsj.81.361

M3 - Article

AN - SCOPUS:58149295124

SN - 0009-2673

VL - 81

SP - 361

EP - 368

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 3

ER -

Novel photoreaction using diphenyl disulfide derivatives: Photoinduced oxidation of allyl alcohol

Abstract

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