Novel high-pressure behavior in chlorite: A synchrotron XRD study of clinochlore to 27 GPa

Mark D. Welch, Annette K. Kleppe, Andrew P. Jephcoat

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    18 Citations (Scopus)

    Abstract

    The high-pressure behavior of synthetic end-member IIb clinochlore, Mg5Al(Si3Al)O10(OH)8, has been studied by synchrotron X-ray powder diffraction to 27 GPa at 300 K. A non-quenchable, reversible transformation occurs between 9 and 10 GPa that is dominated by compression normal to the structural layering and has an associated small but significant shear of the β angle from 97.2 to 96.3°. The high-pressure chlorite is more compressible than the low-pressure phase. Diffraction patterns of the high-pressure chlorite are very similar from 10 to 27 GPa, indicating that it persists stably with no significant change in β to very high pressures: β is effectively locked at the transformation to the high-pressure structure. It is proposed that the transformation is not polytypic and that the distortion reflects reorganization of the interlayer hydrogen bonding, possibly involving novel proton behavior as adjacent sheets of cations of the brucite-like and tetrahedral layers close down on the sheet of interlayer protons. The transformation is likely driven by O atom close-packing requirements imposed by pressure.

    Original languageEnglish
    Pages (from-to)1337-1340
    Number of pages4
    JournalAmerican Mineralogist
    Volume89
    Issue number8-9
    DOIs
    Publication statusPublished - 2004

    ASJC Scopus subject areas

    • Geophysics
    • Geochemistry and Petrology

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