Novel fluorine-containing poly(aryl ether amide)s derived from 2,3,4,5,6-pentafluorobenzoic acid

Ken Tanaka, Natsuko Sato, Shinichi Yamazaki, Kunio Kimura, Yuhiko Yamashita

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Various amide-containing aryl fluorides were synthesized from 2,3,4,5,6-pentafluorobenzoic acid, and novel fifteen AA-BB type and three AB type fluorine-containing poly(aryl ether amide)s (F-PEA) were obtained by nucleophilic aromatic substitution reaction. The synthesized aryl fluorides possessed several reactive carbons for the nucleophilic attack and cross-linking reaction occurred at 100°C. Polymerizations were carried out at 80°C to avoid cross-linking and stopped just before gelation occurred. They had all para connected linear structures. The obtained F-PEAs showed excellent solubility and afforded tough transparent films by casting method. They also exhibited high Tg in the range of 179-273°C depending on the molecular structure. They showed good thermal stability, and even though F-PEAs contained amide linkage into the repeating unit of polymer molecule, they exhibited excellent hydrophobicity due to the incorporation of 2,3,5,6-tetrafluoro-1,4-phenylene moiety.

Original languageEnglish
Pages (from-to)155-161
Number of pages7
JournalJournal of Fiber Science and Technology
Volume62
Issue number7
DOIs
Publication statusPublished - Jan 1 2006

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Polymers and Plastics
  • Industrial and Manufacturing Engineering

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