Novel efficient synthesis and structural analysis of furanose-type phosphono sugars

Mitsuji Yamashita, Akihiro Yabui, Tatsuo Oshikawa, Tadashi Hanaya, Hiroshi Yamamoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Reaction of 2-benzyloxymethyl-1-methoxy-3-phospholene 1-oxide with mCPBA afforded 3,4-epoxyphospholane derivatives, whose isomerized allylic alcohols were cis-dihydroxylated by osmium(VIII) oxide-catalyzed oxidation to give ribo-, arabino-, xylo-, and lyxofuranose-type phosphono sugars. The nmr data suggest a twist conformation.

Original languageEnglish
Pages (from-to)1449-1452
Number of pages4
JournalHeterocycles
Volume38
Issue number7
Publication statusPublished - Jul 1 1994

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Structural analysis
Sugars
Oxides
Osmium
Conformations
Derivatives
Oxidation
allyl alcohol

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Yamashita, M., Yabui, A., Oshikawa, T., Hanaya, T., & Yamamoto, H. (1994). Novel efficient synthesis and structural analysis of furanose-type phosphono sugars. Heterocycles, 38(7), 1449-1452.

Novel efficient synthesis and structural analysis of furanose-type phosphono sugars. / Yamashita, Mitsuji; Yabui, Akihiro; Oshikawa, Tatsuo; Hanaya, Tadashi; Yamamoto, Hiroshi.

In: Heterocycles, Vol. 38, No. 7, 01.07.1994, p. 1449-1452.

Research output: Contribution to journalArticle

Yamashita, M, Yabui, A, Oshikawa, T, Hanaya, T & Yamamoto, H 1994, 'Novel efficient synthesis and structural analysis of furanose-type phosphono sugars', Heterocycles, vol. 38, no. 7, pp. 1449-1452.
Yamashita M, Yabui A, Oshikawa T, Hanaya T, Yamamoto H. Novel efficient synthesis and structural analysis of furanose-type phosphono sugars. Heterocycles. 1994 Jul 1;38(7):1449-1452.
Yamashita, Mitsuji ; Yabui, Akihiro ; Oshikawa, Tatsuo ; Hanaya, Tadashi ; Yamamoto, Hiroshi. / Novel efficient synthesis and structural analysis of furanose-type phosphono sugars. In: Heterocycles. 1994 ; Vol. 38, No. 7. pp. 1449-1452.
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