Novel efficient synthesis and structural analysis of furanose-type phosphono sugars

Mitsuji Yamashita, Akihiro Yabui, Tatsuo Oshikawa, Tadashi Hanaya, Hiroshi Yamamoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Reaction of 2-benzyloxymethyl-1-methoxy-3-phospholene 1-oxide with mCPBA afforded 3,4-epoxyphospholane derivatives, whose isomerized allylic alcohols were cis-dihydroxylated by osmium(VIII) oxide-catalyzed oxidation to give ribo-, arabino-, xylo-, and lyxofuranose-type phosphono sugars. The nmr data suggest a twist conformation.

Original languageEnglish
Pages (from-to)1449-1452
Number of pages4
JournalHeterocycles
Volume38
Issue number7
DOIs
Publication statusPublished - Jul 1 1994

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Novel efficient synthesis and structural analysis of furanose-type phosphono sugars'. Together they form a unique fingerprint.

  • Cite this