Novel configurational structures of sodium tetrakis(3-heptafluorobutylryl- (+)-camphorato) Ln(III) complexes with a trapped Na + by Na +⋯FC interactions in the solid state and in solution

Dai Shirotani, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

For newly prepared sodium tetrakis(3-heplafluorobutylryl-(+)-camphorato) Ln(III) complexes, the X-ray crystal analysis revealed an unprecedented pseudo-achiral dodecahedron (DD-8 (D 2d)), whereas in CHCl 3 solution, the exciton CD and 19F NMR spectra showed a novel chiral Δ-SAPR-8 (C 4) configuration which is stereospecifically formed by a trapped Na + ion with Na +⋯FC (fluorocarbon) interactions.

Original languageEnglish
Pages (from-to)6111-6113
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number16
DOIs
Publication statusPublished - Aug 7 2006
Externally publishedYes

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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