Abstract
A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.
| Original language | English |
|---|---|
| Pages (from-to) | 1767-1770 |
| Number of pages | 4 |
| Journal | Synthesis |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Jun 1 2006 |
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Keywords
- Epoxides
- Ketones
- Rearrangements
- Ring-opening
- Tandem reactions
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Novel and effective synthesis of 2-acyloxy-3-keto esters. / Komiyama, Takuzo; Takaguchi, Yutaka; Tsuboi, Sadao.
In: Synthesis, No. 11, 01.06.2006, p. 1767-1770.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Novel and effective synthesis of 2-acyloxy-3-keto esters
AU - Komiyama, Takuzo
AU - Takaguchi, Yutaka
AU - Tsuboi, Sadao
PY - 2006/6/1
Y1 - 2006/6/1
N2 - A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.
AB - A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.
KW - Epoxides
KW - Ketones
KW - Rearrangements
KW - Ring-opening
KW - Tandem reactions
UR - http://www.scopus.com/inward/record.url?scp=33745141588&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33745141588&partnerID=8YFLogxK
U2 - 10.1055/s-2006-926468
DO - 10.1055/s-2006-926468
M3 - Article
SP - 1767
EP - 1770
JO - Synthesis
JF - Synthesis
SN - 0039-7881
IS - 11
ER -