Novel and effective synthesis of 2-acyloxy-3-keto esters

Takuzo Komiyama, Yutaka Takaguchi, Sadao Tsuboi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.

Original languageEnglish
Pages (from-to)1767-1770
Number of pages4
JournalSynthesis
Issue number11
DOIs
Publication statusPublished - Jun 1 2006

Fingerprint

Esters
Acetonitrile
Salts
acetonitrile

Keywords

  • Epoxides
  • Ketones
  • Rearrangements
  • Ring-opening
  • Tandem reactions

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Novel and effective synthesis of 2-acyloxy-3-keto esters. / Komiyama, Takuzo; Takaguchi, Yutaka; Tsuboi, Sadao.

In: Synthesis, No. 11, 01.06.2006, p. 1767-1770.

Research output: Contribution to journalArticle

Komiyama, Takuzo ; Takaguchi, Yutaka ; Tsuboi, Sadao. / Novel and effective synthesis of 2-acyloxy-3-keto esters. In: Synthesis. 2006 ; No. 11. pp. 1767-1770.
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