Novel and effective synthesis of 2-acyloxy-3-keto esters

Takuzo Komiyama; Yutaka Takaguchi; Sadao Tsuboi

doi:10.1055/s-2006-926468

Novel and effective synthesis of 2-acyloxy-3-keto esters

Takuzo Komiyama, Yutaka Takaguchi, Sadao Tsuboi

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.

Original language	English
Pages (from-to)	1767-1770
Number of pages	4
Journal	Synthesis
Issue number	11
DOIs	https://doi.org/10.1055/s-2006-926468
Publication status	Published - Jun 1 2006

Keywords

Epoxides
Ketones
Rearrangements
Ring-opening
Tandem reactions

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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title = "Novel and effective synthesis of 2-acyloxy-3-keto esters",

abstract = "A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.",

keywords = "Epoxides, Ketones, Rearrangements, Ring-opening, Tandem reactions",

author = "Takuzo Komiyama and Yutaka Takaguchi and Sadao Tsuboi",

year = "2006",

month = jun,

day = "1",

doi = "10.1055/s-2006-926468",

language = "English",

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journal = "Synthesis",

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T1 - Novel and effective synthesis of 2-acyloxy-3-keto esters

AU - Komiyama, Takuzo

AU - Takaguchi, Yutaka

AU - Tsuboi, Sadao

PY - 2006/6/1

Y1 - 2006/6/1

N2 - A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.

AB - A one-pot effective synthesis of 2-acyloxy-3-keto ester is reported. Treatment of 2-chloroglycidic esters with carboxylate salts in acetonitrile provided 2-acyloxy-3-keto esters in excellent to reasonable yields.

KW - Epoxides

KW - Ketones

KW - Rearrangements

KW - Ring-opening

KW - Tandem reactions

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UR - http://www.scopus.com/inward/citedby.url?scp=33745141588&partnerID=8YFLogxK

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DO - 10.1055/s-2006-926468

M3 - Article

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EP - 1770

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 11

ER -

Novel and effective synthesis of 2-acyloxy-3-keto esters

Abstract

Keywords

ASJC Scopus subject areas

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