Nitrogen fixation using vaterite particles of CaCO3 conteining fullerodendrons

Bandana Talukdar, Yutaka Takaguchi, Yuuki Sako, Sadao Tsuboi

Research output: Contribution to conferencePaper

Abstract

Chemical nitrogen fixation have been attracting a great interest in the field of fundamental chemistry and industrial processes. Recently, Nishibayashi and co-workers have reported a new non-metallic process for nitrogen fixation to obtain ammonia in 33% yield by the use of C60:γ-cyclodextrin (1:2) complex and light in homogeneous condition. Meanwhile, we have reported a new fullerodendron which can act as an efficient photosensitizer to generate singlet oxygen. During our studies on the reactivity of the fullerodendron, we found that the direct transformation of N2 into ammonia (NH 3) could be achieved using the fullerodendron. Furthermore, when we use vaterite particles of CaCO3 containing the fullerodendron for nitrogen fixation, the yield of ammonia increased dramatically. This result might be due to better isolation of the fullerene moiety incorporated into vaterite particles of CaCO3 as compared with the pristine fullerodendron in solution.

Original languageEnglish
Number of pages1
Publication statusPublished - Oct 19 2006
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period5/24/065/26/06

Keywords

  • Calcium carbonate
  • Composite
  • Dendron
  • Fullerene
  • Fullerodendron
  • Hybrid material

ASJC Scopus subject areas

  • Engineering(all)

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    Talukdar, B., Takaguchi, Y., Sako, Y., & Tsuboi, S. (2006). Nitrogen fixation using vaterite particles of CaCO3 conteining fullerodendrons. Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.