Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang, Zhenhua Wang, Yasushi Nishihara

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Original languageEnglish
Pages (from-to)10507-10510
Number of pages4
JournalChemical Communications
Volume55
Issue number71
DOIs
Publication statusPublished - Jan 1 2019

Fingerprint

Nickel
Fluorides
Copper
Carbon
Fluorine
Silicon
Functional groups

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides. / Wang, Xiu; Wang, Zhenhua; Nishihara, Yasushi.

In: Chemical Communications, Vol. 55, No. 71, 01.01.2019, p. 10507-10510.

Research output: Contribution to journalArticle

Wang, Xiu ; Wang, Zhenhua ; Nishihara, Yasushi. / Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides. In: Chemical Communications. 2019 ; Vol. 55, No. 71. pp. 10507-10510.
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