Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang, Zhenhua Wang, Yasushi Nishihara

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Original languageEnglish
Pages (from-to)10507-10510
Number of pages4
JournalChemical Communications
Volume55
Issue number71
DOIs
Publication statusPublished - Jan 1 2019

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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