Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang; Zhenhua Wang; Yasushi Nishihara

doi:10.1039/c9cc05325e

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang, Zhenhua Wang, Yasushi Nishihara

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Original language	English
Pages (from-to)	10507-10510
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	71
DOIs	https://doi.org/10.1039/c9cc05325e
Publication status	Published - 2019

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c9cc05325e

Fingerprint Dive into the research topics of 'Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides'. Together they form a unique fingerprint.

Cite this

@article{a5b1a5e230bb4854a00d7a657e581c3c,

title = "Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides",

abstract = "Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.",

author = "Xiu Wang and Zhenhua Wang and Yasushi Nishihara",

note = "Funding Information: This study was partly supported by the Marubun Research Promotion Foundation. We gratefully thank the SC-NMR Laboratory (Okayama University) for the NMR spectral measurements. Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2019",

doi = "10.1039/c9cc05325e",

language = "English",

volume = "55",

pages = "10507--10510",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "71",

}

TY - JOUR

T1 - Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

AU - Wang, Xiu

AU - Wang, Zhenhua

AU - Nishihara, Yasushi

N1 - Funding Information: This study was partly supported by the Marubun Research Promotion Foundation. We gratefully thank the SC-NMR Laboratory (Okayama University) for the NMR spectral measurements. Publisher Copyright: This journal is © The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2019

Y1 - 2019

N2 - Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

AB - Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

UR - http://www.scopus.com/inward/record.url?scp=85071615982&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85071615982&partnerID=8YFLogxK

U2 - 10.1039/c9cc05325e

DO - 10.1039/c9cc05325e

M3 - Article

C2 - 31407738

AN - SCOPUS:85071615982

VL - 55

SP - 10507

EP - 10510

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 71

ER -