Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang; Zhenhua Wang; Yasushi Nishihara

doi:10.1039/c9cc05325e

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang, Zhenhua Wang, Yasushi Nishihara

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Original language	English
Pages (from-to)	10507-10510
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	71
DOIs	https://doi.org/10.1039/c9cc05325e
Publication status	Published - Jan 1 2019

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Wang, X., Wang, Z., & Nishihara, Y. (2019). Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides. Chemical Communications, 55(71), 10507-10510. https://doi.org/10.1039/c9cc05325e

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Access to Document

10.1039/c9cc05325e