Abstract
Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.
| Original language | English |
|---|---|
| Pages (from-to) | 10507-10510 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 71 |
| DOIs | |
| Publication status | Published - Jan 1 2019 |
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ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides. / Wang, Xiu; Wang, Zhenhua; Nishihara, Yasushi.
In: Chemical Communications, Vol. 55, No. 71, 01.01.2019, p. 10507-10510.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides
AU - Wang, Xiu
AU - Wang, Zhenhua
AU - Nishihara, Yasushi
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.
AB - Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.
UR - http://www.scopus.com/inward/record.url?scp=85071615982&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85071615982&partnerID=8YFLogxK
U2 - 10.1039/c9cc05325e
DO - 10.1039/c9cc05325e
M3 - Article
C2 - 31407738
AN - SCOPUS:85071615982
VL - 55
SP - 10507
EP - 10510
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 71
ER -