Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang; Zhenhua Wang; Yasushi Nishihara

doi:10.1039/c9cc05325e

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang, Zhenhua Wang, Yasushi Nishihara

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Original language	English
Pages (from-to)	10507-10510
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	71
DOIs	https://doi.org/10.1039/c9cc05325e
Publication status	Published - 2019

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides",

abstract = "Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.",

author = "Xiu Wang and Zhenhua Wang and Yasushi Nishihara",

note = "Funding Information: This study was partly supported by the Marubun Research Promotion Foundation. We gratefully thank the SC-NMR Laboratory (Okayama University) for the NMR spectral measurements. Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

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doi = "10.1039/c9cc05325e",

language = "English",

volume = "55",

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T1 - Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

AU - Wang, Xiu

AU - Wang, Zhenhua

AU - Nishihara, Yasushi

N1 - Funding Information: This study was partly supported by the Marubun Research Promotion Foundation. We gratefully thank the SC-NMR Laboratory (Okayama University) for the NMR spectral measurements. Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

AB - Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

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JF - Chemical Communications

SN - 1359-7345

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ER -

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Abstract

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