Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Xiu Wang, Zhenhua Wang, Yasushi Nishihara

    Research output: Contribution to journalArticlepeer-review

    29 Citations (Scopus)

    Abstract

    Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

    Original languageEnglish
    Pages (from-to)10507-10510
    Number of pages4
    JournalChemical Communications
    Volume55
    Issue number71
    DOIs
    Publication statusPublished - 2019

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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