Abstract
Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.
| Original language | English |
|---|---|
| Pages (from-to) | 10507-10510 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 71 |
| DOIs | |
| Publication status | Published - Jan 1 2019 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Cite this
Wang, X., Wang, Z., & Nishihara, Y. (2019). Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides. Chemical Communications, 55(71), 10507-10510. https://doi.org/10.1039/c9cc05325e