Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Jingwen You, Qiang Chen, Yasushi Nishihara

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

Original languageEnglish
Pages (from-to)3045-3050
Number of pages6
JournalSynthesis (Germany)
Volume53
Issue number17
DOIs
Publication statusPublished - Sep 1 2021

Keywords

  • C-F bond activation
  • acyl fluorides
  • decarbonylation
  • sulfides
  • thioetherification

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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