Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Jingwen You; Qiang Chen; Yasushi Nishihara

doi:10.1055/a-1484-6216

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Jingwen You, Qiang Chen, Yasushi Nishihara

Research output: Contribution to journal › Article › peer-review

Abstract

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

Original language	English
Pages (from-to)	3045-3050
Number of pages	6
Journal	Synthesis (Germany)
Volume	53
Issue number	17
DOIs	https://doi.org/10.1055/a-1484-6216
Publication status	Published - Sep 1 2021

Keywords

C-F bond activation
acyl fluorides
decarbonylation
sulfides
thioetherification

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/a-1484-6216

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keywords = "C-F bond activation, acyl fluorides, decarbonylation, sulfides, thioetherification",

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AU - Nishihara, Yasushi

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Y1 - 2021/9/1

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AB - Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

KW - C-F bond activation

KW - acyl fluorides

KW - decarbonylation

KW - sulfides

KW - thioetherification

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Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Abstract

Keywords

ASJC Scopus subject areas

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