Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Jingwen You, Qiang Chen, Yasushi Nishihara

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

    Original languageEnglish
    Pages (from-to)3045-3050
    Number of pages6
    JournalSynthesis (Germany)
    Volume53
    Issue number17
    DOIs
    Publication statusPublished - Sep 1 2021

    Keywords

    • C-F bond activation
    • acyl fluorides
    • decarbonylation
    • sulfides
    • thioetherification

    ASJC Scopus subject areas

    • Catalysis
    • Organic Chemistry

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