Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Jingwen You; Qiang Chen; Yasushi Nishihara

doi:10.1055/a-1484-6216

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Jingwen You, Qiang Chen, Yasushi Nishihara

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

Original language	English
Pages (from-to)	3045-3050
Number of pages	6
Journal	Synthesis (Germany)
Volume	53
Issue number	17
DOIs	https://doi.org/10.1055/a-1484-6216
Publication status	Published - Sep 1 2021

Keywords

C-F bond activation
acyl fluorides
decarbonylation
sulfides
thioetherification

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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abstract = "Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.",

keywords = "C-F bond activation, acyl fluorides, decarbonylation, sulfides, thioetherification",

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AU - Nishihara, Yasushi

PY - 2021/9/1

Y1 - 2021/9/1

N2 - Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

AB - Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

KW - C-F bond activation

KW - acyl fluorides

KW - decarbonylation

KW - sulfides

KW - thioetherification

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ER -

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Abstract

Keywords

ASJC Scopus subject areas

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