Nickel-catalysed decarbonylative borylation of aroyl fluorides

Zhenhua Wang; Xiu Wang; Yasushi Nishihara

doi:10.1039/c8cc08504h

Nickel-catalysed decarbonylative borylation of aroyl fluorides

Zhenhua Wang, Xiu Wang, Yasushi Nishihara

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

The first Ni(cod)₂/PPh₃ catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.

Original language	English
Pages (from-to)	13969-13972
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	99
DOIs	https://doi.org/10.1039/c8cc08504h
Publication status	Published - 2018

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Nickel-catalysed decarbonylative borylation of aroyl fluorides",

abstract = "The first Ni(cod)2/PPh3 catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.",

author = "Zhenhua Wang and Xiu Wang and Yasushi Nishihara",

note = "Funding Information: This study was partly supported by ACT-C, JST Grant JPMJCR12YW, Japan. The authors gratefully thank Ms Megumi Kosaka and Mr Motonari Kobayashi at the Department of Instrumental Analysis, Advanced Science Research Centre, Okayama University for the measurements of elemental analyses and the SC-NMR Laboratory of Okayama University for the NMR spectral measurements. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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doi = "10.1039/c8cc08504h",

language = "English",

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pages = "13969--13972",

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T1 - Nickel-catalysed decarbonylative borylation of aroyl fluorides

AU - Wang, Zhenhua

AU - Wang, Xiu

AU - Nishihara, Yasushi

N1 - Funding Information: This study was partly supported by ACT-C, JST Grant JPMJCR12YW, Japan. The authors gratefully thank Ms Megumi Kosaka and Mr Motonari Kobayashi at the Department of Instrumental Analysis, Advanced Science Research Centre, Okayama University for the measurements of elemental analyses and the SC-NMR Laboratory of Okayama University for the NMR spectral measurements. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018

Y1 - 2018

N2 - The first Ni(cod)2/PPh3 catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.

AB - The first Ni(cod)2/PPh3 catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.

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EP - 13972

JO - Chemical Communications

JF - Chemical Communications

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ER -

Nickel-catalysed decarbonylative borylation of aroyl fluorides

Abstract

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