New stable complexes of Au(III) with biuret

X-ray structure of cis-[Au(Biu)Br2]PPh4 and Ab initio investigation of cis-[Au(Biu)X2]-

N. Mintcheva, M. Mitewa, V. Enchev, Yasushi Nishihara

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Two anionic complexes of Au(III) with the bioligand biuret, cis-[Au(Biu)X2]- (BiuH2 = biuret, X = Cl, Br), have been synthesized and characterized. The molecular structure of cis-[Au(Biu)Br2]PPh4 has been determined by X-ray diffraction analysis. The complex anion has square-planar geometry with one deprotonated biuret dianion coordinated bidentately to the metal center via the terminal amino nitrogen atoms and two bromide ions in cis positions. There are no significant intermolecular Au-Au interactions in the solid state. Ab initio calculations of the geometric structure at different computational levels for biuret and both anionic complexes as well an IR study of the structures obtained are performed.

Original languageEnglish
Pages (from-to)299-305
Number of pages7
JournalJournal of Coordination Chemistry
Volume56
Issue number4
DOIs
Publication statusPublished - Mar 10 2003
Externally publishedYes

Fingerprint

Biuret
nitrogen atoms
X ray diffraction analysis
Molecular structure
bromides
molecular structure
Negative ions
anions
Nitrogen
solid state
X rays
Atoms
Geometry
Ions
geometry
Metals
diffraction
metals
ions
x rays

Keywords

  • Ab initio calculations
  • Au(III) complexes
  • Biuret
  • IR study
  • X-ray data

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

New stable complexes of Au(III) with biuret : X-ray structure of cis-[Au(Biu)Br2]PPh4 and Ab initio investigation of cis-[Au(Biu)X2]-. / Mintcheva, N.; Mitewa, M.; Enchev, V.; Nishihara, Yasushi.

In: Journal of Coordination Chemistry, Vol. 56, No. 4, 10.03.2003, p. 299-305.

Research output: Contribution to journalArticle

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AU - Nishihara, Yasushi

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AB - Two anionic complexes of Au(III) with the bioligand biuret, cis-[Au(Biu)X2]- (BiuH2 = biuret, X = Cl, Br), have been synthesized and characterized. The molecular structure of cis-[Au(Biu)Br2]PPh4 has been determined by X-ray diffraction analysis. The complex anion has square-planar geometry with one deprotonated biuret dianion coordinated bidentately to the metal center via the terminal amino nitrogen atoms and two bromide ions in cis positions. There are no significant intermolecular Au-Au interactions in the solid state. Ab initio calculations of the geometric structure at different computational levels for biuret and both anionic complexes as well an IR study of the structures obtained are performed.

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