New polymorph of barium chloroanilate trihydrate

Setsuo Kashino, Hiroyuki Ishida, Takeo Fukunaga, Shuji Oishi

Research output: Contribution to journalArticle

Abstract

Single crystals of a new polymorph of the title compound, barium(II) 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone tri- hydrate, Ba2+·C6Cl2O4 2-·3H2O, have been grown in sodium metasilicate gel. Each Ba2+ cation is coordinated by eight O atoms. The Ba2+ cations are bridged by an O atom of a ligand around the centre of symmetry at Wyckoff position 4a and by the O atom of a water molecule around the centre of symmetry at Wyckoff position 4b, forming a sheet parallel to the (100) plane. Loose contacts are found around one of the water molecules, as observed in the Cmca form.

Original languageEnglish
Pages (from-to)18-19
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume57
Issue number1
DOIs
Publication statusPublished - Jan 2001

Fingerprint

Barium
Polymorphism
Barium Compounds
barium
Cations
Atoms
Water
barium compounds
atoms
cations
Molecules
Gels
quinones
symmetry
Ligands
Hydrates
hydrates
water
molecules
sodium

ASJC Scopus subject areas

  • Structural Biology
  • Condensed Matter Physics

Cite this

New polymorph of barium chloroanilate trihydrate. / Kashino, Setsuo; Ishida, Hiroyuki; Fukunaga, Takeo; Oishi, Shuji.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 57, No. 1, 01.2001, p. 18-19.

Research output: Contribution to journalArticle

Kashino, Setsuo ; Ishida, Hiroyuki ; Fukunaga, Takeo ; Oishi, Shuji. / New polymorph of barium chloroanilate trihydrate. In: Acta Crystallographica Section C: Crystal Structure Communications. 2001 ; Vol. 57, No. 1. pp. 18-19.
@article{64e072bb122e42a486b3e85d28b7a00c,
title = "New polymorph of barium chloroanilate trihydrate",
abstract = "Single crystals of a new polymorph of the title compound, barium(II) 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone tri- hydrate, Ba2+·C6Cl2O4 2-·3H2O, have been grown in sodium metasilicate gel. Each Ba2+ cation is coordinated by eight O atoms. The Ba2+ cations are bridged by an O atom of a ligand around the centre of symmetry at Wyckoff position 4a and by the O atom of a water molecule around the centre of symmetry at Wyckoff position 4b, forming a sheet parallel to the (100) plane. Loose contacts are found around one of the water molecules, as observed in the Cmca form.",
author = "Setsuo Kashino and Hiroyuki Ishida and Takeo Fukunaga and Shuji Oishi",
year = "2001",
month = "1",
doi = "10.1107/S0108270100013639",
language = "English",
volume = "57",
pages = "18--19",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "1",

}

TY - JOUR

T1 - New polymorph of barium chloroanilate trihydrate

AU - Kashino, Setsuo

AU - Ishida, Hiroyuki

AU - Fukunaga, Takeo

AU - Oishi, Shuji

PY - 2001/1

Y1 - 2001/1

N2 - Single crystals of a new polymorph of the title compound, barium(II) 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone tri- hydrate, Ba2+·C6Cl2O4 2-·3H2O, have been grown in sodium metasilicate gel. Each Ba2+ cation is coordinated by eight O atoms. The Ba2+ cations are bridged by an O atom of a ligand around the centre of symmetry at Wyckoff position 4a and by the O atom of a water molecule around the centre of symmetry at Wyckoff position 4b, forming a sheet parallel to the (100) plane. Loose contacts are found around one of the water molecules, as observed in the Cmca form.

AB - Single crystals of a new polymorph of the title compound, barium(II) 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone tri- hydrate, Ba2+·C6Cl2O4 2-·3H2O, have been grown in sodium metasilicate gel. Each Ba2+ cation is coordinated by eight O atoms. The Ba2+ cations are bridged by an O atom of a ligand around the centre of symmetry at Wyckoff position 4a and by the O atom of a water molecule around the centre of symmetry at Wyckoff position 4b, forming a sheet parallel to the (100) plane. Loose contacts are found around one of the water molecules, as observed in the Cmca form.

UR - http://www.scopus.com/inward/record.url?scp=0034831458&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034831458&partnerID=8YFLogxK

U2 - 10.1107/S0108270100013639

DO - 10.1107/S0108270100013639

M3 - Article

C2 - 11173382

AN - SCOPUS:0034831458

VL - 57

SP - 18

EP - 19

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 1

ER -