Nanostructured Mn oxide/carboxylic acid or amine functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis

Mohammad Mahdi Najafpour, Saeideh Salimi, Małgorzata Hołyńska, Fahime Rahimi, Mojtaba Tavahodi, Tatsuya Tomo, Suleyman Allakhverdiev

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Herein, we report on nano-sized Mn oxide/carboxylic acid or amine-functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis. The composites are synthesized by simple procedures and characterized by different methods. The water-oxidizing activities of these composites are also considered in the presence of cerium (IV) ammonium nitrate and Ru(bpy)3 3+ in a photochemical reaction. Some composites are efficient Mn-based catalysts with turnover frequency (TOF, mmolO2/(mol Mn·s)) of more than 1.

Original languageEnglish
Title of host publicationPhotosynthesis
Subtitle of host publicationStructures, Mechanisms, and Applications
PublisherSpringer International Publishing
Pages321-331
Number of pages11
ISBN (Electronic)9783319488738
ISBN (Print)9783319488714
DOIs
Publication statusPublished - May 16 2017
Externally publishedYes

Fingerprint

carbon nanotubes
manganese oxides
Carbon Nanotubes
Photosynthesis
composite materials
carboxylic acids
Carboxylic Acids
amines
Carboxylic acids
Oxides
Amines
Carbon nanotubes
photosynthesis
Water
Composite materials
water
photochemical reactions
Photochemical reactions
Cerium
catalysts

Keywords

  • Artificial photosynthesis
  • Carbon nanotube
  • Cerium
  • Composite
  • Manganese
  • Manganese oxide
  • Nanostructure
  • Water oxidation
  • Water splitting

ASJC Scopus subject areas

  • Agricultural and Biological Sciences(all)
  • Engineering(all)
  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Najafpour, M. M., Salimi, S., Hołyńska, M., Rahimi, F., Tavahodi, M., Tomo, T., & Allakhverdiev, S. (2017). Nanostructured Mn oxide/carboxylic acid or amine functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis. In Photosynthesis: Structures, Mechanisms, and Applications (pp. 321-331). Springer International Publishing. https://doi.org/10.1007/978-3-319-48873-8_15

Nanostructured Mn oxide/carboxylic acid or amine functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis. / Najafpour, Mohammad Mahdi; Salimi, Saeideh; Hołyńska, Małgorzata; Rahimi, Fahime; Tavahodi, Mojtaba; Tomo, Tatsuya; Allakhverdiev, Suleyman.

Photosynthesis: Structures, Mechanisms, and Applications. Springer International Publishing, 2017. p. 321-331.

Research output: Chapter in Book/Report/Conference proceedingChapter

Najafpour, MM, Salimi, S, Hołyńska, M, Rahimi, F, Tavahodi, M, Tomo, T & Allakhverdiev, S 2017, Nanostructured Mn oxide/carboxylic acid or amine functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis. in Photosynthesis: Structures, Mechanisms, and Applications. Springer International Publishing, pp. 321-331. https://doi.org/10.1007/978-3-319-48873-8_15
Najafpour MM, Salimi S, Hołyńska M, Rahimi F, Tavahodi M, Tomo T et al. Nanostructured Mn oxide/carboxylic acid or amine functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis. In Photosynthesis: Structures, Mechanisms, and Applications. Springer International Publishing. 2017. p. 321-331 https://doi.org/10.1007/978-3-319-48873-8_15
Najafpour, Mohammad Mahdi ; Salimi, Saeideh ; Hołyńska, Małgorzata ; Rahimi, Fahime ; Tavahodi, Mojtaba ; Tomo, Tatsuya ; Allakhverdiev, Suleyman. / Nanostructured Mn oxide/carboxylic acid or amine functionalized carbon nanotubes as water-oxidizing composites in artificial photosynthesis. Photosynthesis: Structures, Mechanisms, and Applications. Springer International Publishing, 2017. pp. 321-331
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