Nanocrystalline magnesium oxide-stabilized palladium(0): The Heck reaction of heteroaryl bromides in the absence of additional ligands and base

Mannepalli Lakshmi Kantam; Police Vishnuvardhan Redddy; Pottabathula Srinivas; Akula Venugopal; Suresh Bhargava; Yuta Nishina

doi:10.1039/c3cy00404j

Nanocrystalline magnesium oxide-stabilized palladium(0): The Heck reaction of heteroaryl bromides in the absence of additional ligands and base

Mannepalli Lakshmi Kantam, Police Vishnuvardhan Redddy, Pottabathula Srinivas, Akula Venugopal, Suresh Bhargava, Yuta Nishina

Research Core for Interdisciplinary Sciences

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.

Original language	English
Pages (from-to)	2550-2554
Number of pages	5
Journal	Catalysis Science and Technology
Volume	3
Issue number	10
DOIs	https://doi.org/10.1039/c3cy00404j
Publication status	Published - Oct 2013

ASJC Scopus subject areas

Catalysis

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10.1039/c3cy00404j

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Nanocrystalline magnesium oxide-stabilized palladium(0) : The Heck reaction of heteroaryl bromides in the absence of additional ligands and base. / Kantam, Mannepalli Lakshmi; Redddy, Police Vishnuvardhan; Srinivas, Pottabathula; Venugopal, Akula; Bhargava, Suresh; Nishina, Yuta.

In: Catalysis Science and Technology, Vol. 3, No. 10, 10.2013, p. 2550-2554.

Research output: Contribution to journal › Article › peer-review

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