Abstract
An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.
| Original language | English |
|---|---|
| Pages (from-to) | 2550-2554 |
| Number of pages | 5 |
| Journal | Catalysis Science and Technology |
| Volume | 3 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - Oct 2013 |
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ASJC Scopus subject areas
- Catalysis
Cite this
Nanocrystalline magnesium oxide-stabilized palladium(0) : The Heck reaction of heteroaryl bromides in the absence of additional ligands and base. / Kantam, Mannepalli Lakshmi; Redddy, Police Vishnuvardhan; Srinivas, Pottabathula; Venugopal, Akula; Bhargava, Suresh; Nishina, Yuta.
In: Catalysis Science and Technology, Vol. 3, No. 10, 10.2013, p. 2550-2554.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nanocrystalline magnesium oxide-stabilized palladium(0)
T2 - The Heck reaction of heteroaryl bromides in the absence of additional ligands and base
AU - Kantam, Mannepalli Lakshmi
AU - Redddy, Police Vishnuvardhan
AU - Srinivas, Pottabathula
AU - Venugopal, Akula
AU - Bhargava, Suresh
AU - Nishina, Yuta
PY - 2013/10
Y1 - 2013/10
N2 - An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.
AB - An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.
UR - http://www.scopus.com/inward/record.url?scp=84884133936&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84884133936&partnerID=8YFLogxK
U2 - 10.1039/c3cy00404j
DO - 10.1039/c3cy00404j
M3 - Article
AN - SCOPUS:84884133936
VL - 3
SP - 2550
EP - 2554
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
SN - 2044-4753
IS - 10
ER -