Nanocrystalline magnesium oxide-stabilized palladium(0): The Heck reaction of heteroaryl bromides in the absence of additional ligands and base

Mannepalli Lakshmi Kantam, Police Vishnuvardhan Redddy, Pottabathula Srinivas, Akula Venugopal, Suresh Bhargava, Yuta Nishina

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.

Original languageEnglish
Pages (from-to)2550-2554
Number of pages5
JournalCatalysis Science and Technology
Volume3
Issue number10
DOIs
Publication statusPublished - Oct 1 2013

ASJC Scopus subject areas

  • Catalysis

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