Nanocrystalline magnesium oxide-stabilized palladium(0): The Heck reaction of heteroaryl bromides in the absence of additional ligands and base

Mannepalli Lakshmi Kantam, Police Vishnuvardhan Redddy, Pottabathula Srinivas, Akula Venugopal, Suresh Bhargava, Yuta Nishina

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.

Original languageEnglish
Pages (from-to)2550-2554
Number of pages5
JournalCatalysis Science and Technology
Volume3
Issue number10
DOIs
Publication statusPublished - Oct 2013

Fingerprint

Magnesium Oxide
Magnesia
Palladium
Bromides
Ligands
Catalysts
Decomposition

ASJC Scopus subject areas

  • Catalysis

Cite this

Nanocrystalline magnesium oxide-stabilized palladium(0) : The Heck reaction of heteroaryl bromides in the absence of additional ligands and base. / Kantam, Mannepalli Lakshmi; Redddy, Police Vishnuvardhan; Srinivas, Pottabathula; Venugopal, Akula; Bhargava, Suresh; Nishina, Yuta.

In: Catalysis Science and Technology, Vol. 3, No. 10, 10.2013, p. 2550-2554.

Research output: Contribution to journalArticle

Kantam, Mannepalli Lakshmi ; Redddy, Police Vishnuvardhan ; Srinivas, Pottabathula ; Venugopal, Akula ; Bhargava, Suresh ; Nishina, Yuta. / Nanocrystalline magnesium oxide-stabilized palladium(0) : The Heck reaction of heteroaryl bromides in the absence of additional ligands and base. In: Catalysis Science and Technology. 2013 ; Vol. 3, No. 10. pp. 2550-2554.
@article{71ae8bd5adda4a66a98f9c62d10ad9d9,
title = "Nanocrystalline magnesium oxide-stabilized palladium(0): The Heck reaction of heteroaryl bromides in the absence of additional ligands and base",
abstract = "An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.",
author = "Kantam, {Mannepalli Lakshmi} and Redddy, {Police Vishnuvardhan} and Pottabathula Srinivas and Akula Venugopal and Suresh Bhargava and Yuta Nishina",
year = "2013",
month = "10",
doi = "10.1039/c3cy00404j",
language = "English",
volume = "3",
pages = "2550--2554",
journal = "Catalysis Science and Technology",
issn = "2044-4753",
publisher = "Royal Society of Chemistry",
number = "10",

}

TY - JOUR

T1 - Nanocrystalline magnesium oxide-stabilized palladium(0)

T2 - The Heck reaction of heteroaryl bromides in the absence of additional ligands and base

AU - Kantam, Mannepalli Lakshmi

AU - Redddy, Police Vishnuvardhan

AU - Srinivas, Pottabathula

AU - Venugopal, Akula

AU - Bhargava, Suresh

AU - Nishina, Yuta

PY - 2013/10

Y1 - 2013/10

N2 - An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.

AB - An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.

UR - http://www.scopus.com/inward/record.url?scp=84884133936&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84884133936&partnerID=8YFLogxK

U2 - 10.1039/c3cy00404j

DO - 10.1039/c3cy00404j

M3 - Article

AN - SCOPUS:84884133936

VL - 3

SP - 2550

EP - 2554

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

SN - 2044-4753

IS - 10

ER -