Nano-sized ceramic particles of hydroxyapatite calcined with an anti-sintering agent

Masahiro Okada, Tsutomu Furuzono

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Nano-sized crystals of calcined hydroxyapatite (HAp) having spherical morphologies were fabricated by calcination at 800°for 1 h with an anti-sintering agent surrounding the original HAp particles and the agent was subsequently removed by washing after calcination. The original HAp particles were prepared by a modified emulsion system, and surrounded with poly(acrylic acid, calcium salt) (PAA-Ca) by utilizing a precipitation reaction between calcium hydroxide and poly(acrylic acid) adsorbed on the HAp particle surfaces in an aqueous medium. In the case of calcination without PAA-Ca, micron-sized particles consisting of sintered polycrystals were mainly observed by scanning electron microscopy, indicating the calcination-induced sintering among the crystals. On the other hand, most of the crystals calcined with the anti-sintering agent were observed as isolated particles, and the mean size of the HAp crystals was around 80 nm. This result indicates that PAA-Ca and its thermally decomposed product, CaO, surrounding the HAp crystals could protect them against calcination-induced sintering during calcination at 800°The HAp crystals calcined with PAA-Ca showed high crystallinity, and no other calcium phosphate phases could be detected.

Original languageEnglish
Pages (from-to)848-851
Number of pages4
JournalJournal of Nanoscience and Nanotechnology
Volume7
Issue number3
DOIs
Publication statusPublished - Mar 1 2007
Externally publishedYes

Keywords

  • Calcination
  • Ceramics
  • Dispersibility
  • Hydroxyapatite
  • Nano

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics

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