Multitracer study on permeation of rare earth elements through a supported liquid membrane

S. Ambe, K. Yashiki, H. Maeda, S. Enomoto, T. Ozaki, F. Ambe

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Separation by means of supported liquid membranes is a useful method for the preparation and preconcentration of radioactive nuclides. The permeation of rare earth elements through a bis(2-ethylhexyl) hydrogen phosphate- decalin membrane supported on a microporous polytetrafluoroethylene sheet was studied using a multitracer containing radioactive nuclides of Sc, Zr, Nb, Hf, Ce, Pm, Gd, Yb, and Lu. Permeation rates of these elements from feed solutions of various acidity to receiving solutions of 0.5 mol · dm-3 HCl were determined simultaneously. The feed solution at pH 1.4 gave the highest permeation rate for Ce, Pm, and Gd, amounting to about 95% of permeation for Ce and Pm, 80% for Gd, and 10% for Yb in 21 h. Scandium, Zr, Nb, Hf, and Lu were not transported at all from the feed solution. Permeation rates of Yb and Lu from the feed solution at pH 1.4 to receiving solutions of 0.75, 1.0, 2.3, and 4.0 mol · dm-3 HCl increased with the concentration. The results obtained indicate that the light rare earth elements can be separated from the heavy ones by this method.

Original languageEnglish
Pages (from-to)181-185
Number of pages5
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume236
Issue number1-2
DOIs
Publication statusPublished - Nov 2 1998

ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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