Abstract
Potassium salts of cobalt(III) and manganese(III) complexes, K[CoL(py)2]·2EtOH·MeOH 1 and K[MnL(py)2]·py 2, have been prepared, where H4L= 1,2-bis(hydroxybenzamido)benzene and py = pyridine. 1 crystallizes in the monoclinic space group P21/n with the cell dimensions of a= 12.688(3), b= 17.555(4), c= 16.673(3) Å, β = 102.59(2)°, V= 3624(1) ̊3 and Z = 4, in which potassium ion plays a role of connector for two adjacent [CoL(py)2]- molecules through K-O interaction (two phenoxo oxygen atoms of a cobalt(III) complex, two oxygen atoms of the solvent molecules, and an amido oxygen of the adjacent unit) to give an extended one-dimensional structure. 2 crystallizes in the orthorhombic space group P212121 with the cell dimensions of a= 14.358(1), b= 16.457(2), c= 13.703(2) Å3, V = 3237.7(5) Å3 and Z = 4, in which potassium ion plays a role of connector for three adjacent [MnL(py)2]- molecules through K-O interaction to give an extended three-dimensional structure.
| Original language | English |
|---|---|
| Pages (from-to) | 167-173 |
| Number of pages | 7 |
| Journal | Bulletin of the Chemical Society of Japan |
| Volume | 71 |
| Issue number | 1 |
| Publication status | Published - Jan 1998 |
| Externally published | Yes |
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Multi-Dimensional Structures Constructed by the Electrostatic Interaction of Potassium Salts of Cobalt(III) and Manganese(III) Complexes with 1,2-Bis(2-hydroxybenzamido)benzene. / Sunatsuki, Yukinari; Mimura, Masaaki; Shimada, Hirotnitsu; Kai, Fumiaki; Matsumoto, Naohide.
In: Bulletin of the Chemical Society of Japan, Vol. 71, No. 1, 01.1998, p. 167-173.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Multi-Dimensional Structures Constructed by the Electrostatic Interaction of Potassium Salts of Cobalt(III) and Manganese(III) Complexes with 1,2-Bis(2-hydroxybenzamido)benzene
AU - Sunatsuki, Yukinari
AU - Mimura, Masaaki
AU - Shimada, Hirotnitsu
AU - Kai, Fumiaki
AU - Matsumoto, Naohide
PY - 1998/1
Y1 - 1998/1
N2 - Potassium salts of cobalt(III) and manganese(III) complexes, K[CoL(py)2]·2EtOH·MeOH 1 and K[MnL(py)2]·py 2, have been prepared, where H4L= 1,2-bis(hydroxybenzamido)benzene and py = pyridine. 1 crystallizes in the monoclinic space group P21/n with the cell dimensions of a= 12.688(3), b= 17.555(4), c= 16.673(3) Å, β = 102.59(2)°, V= 3624(1) ̊3 and Z = 4, in which potassium ion plays a role of connector for two adjacent [CoL(py)2]- molecules through K-O interaction (two phenoxo oxygen atoms of a cobalt(III) complex, two oxygen atoms of the solvent molecules, and an amido oxygen of the adjacent unit) to give an extended one-dimensional structure. 2 crystallizes in the orthorhombic space group P212121 with the cell dimensions of a= 14.358(1), b= 16.457(2), c= 13.703(2) Å3, V = 3237.7(5) Å3 and Z = 4, in which potassium ion plays a role of connector for three adjacent [MnL(py)2]- molecules through K-O interaction to give an extended three-dimensional structure.
AB - Potassium salts of cobalt(III) and manganese(III) complexes, K[CoL(py)2]·2EtOH·MeOH 1 and K[MnL(py)2]·py 2, have been prepared, where H4L= 1,2-bis(hydroxybenzamido)benzene and py = pyridine. 1 crystallizes in the monoclinic space group P21/n with the cell dimensions of a= 12.688(3), b= 17.555(4), c= 16.673(3) Å, β = 102.59(2)°, V= 3624(1) ̊3 and Z = 4, in which potassium ion plays a role of connector for two adjacent [CoL(py)2]- molecules through K-O interaction (two phenoxo oxygen atoms of a cobalt(III) complex, two oxygen atoms of the solvent molecules, and an amido oxygen of the adjacent unit) to give an extended one-dimensional structure. 2 crystallizes in the orthorhombic space group P212121 with the cell dimensions of a= 14.358(1), b= 16.457(2), c= 13.703(2) Å3, V = 3237.7(5) Å3 and Z = 4, in which potassium ion plays a role of connector for three adjacent [MnL(py)2]- molecules through K-O interaction to give an extended three-dimensional structure.
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M3 - Article
AN - SCOPUS:0001468284
VL - 71
SP - 167
EP - 173
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
SN - 0009-2673
IS - 1
ER -