Multi-Dimensional Structures Constructed by the Electrostatic Interaction of Potassium Salts of Cobalt(III) and Manganese(III) Complexes with 1,2-Bis(2-hydroxybenzamido)benzene

Yukinari Sunatsuki, Masaaki Mimura, Hirotnitsu Shimada, Fumiaki Kai, Naohide Matsumoto

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Abstract

Potassium salts of cobalt(III) and manganese(III) complexes, K[CoL(py)2]·2EtOH·MeOH 1 and K[MnL(py)2]·py 2, have been prepared, where H4L= 1,2-bis(hydroxybenzamido)benzene and py = pyridine. 1 crystallizes in the monoclinic space group P21/n with the cell dimensions of a= 12.688(3), b= 17.555(4), c= 16.673(3) Å, β = 102.59(2)°, V= 3624(1) ̊3 and Z = 4, in which potassium ion plays a role of connector for two adjacent [CoL(py)2]- molecules through K-O interaction (two phenoxo oxygen atoms of a cobalt(III) complex, two oxygen atoms of the solvent molecules, and an amido oxygen of the adjacent unit) to give an extended one-dimensional structure. 2 crystallizes in the orthorhombic space group P212121 with the cell dimensions of a= 14.358(1), b= 16.457(2), c= 13.703(2) Å3, V = 3237.7(5) Å3 and Z = 4, in which potassium ion plays a role of connector for three adjacent [MnL(py)2]- molecules through K-O interaction to give an extended three-dimensional structure.

Original languageEnglish
Pages (from-to)167-173
Number of pages7
JournalBulletin of the Chemical Society of Japan
Volume71
Issue number1
Publication statusPublished - Jan 1998
Externally publishedYes

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Manganese
Cobalt
Coulomb interactions
Benzene
Potassium
Salts
Oxygen
Molecules
Ions
Atoms

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Multi-Dimensional Structures Constructed by the Electrostatic Interaction of Potassium Salts of Cobalt(III) and Manganese(III) Complexes with 1,2-Bis(2-hydroxybenzamido)benzene. / Sunatsuki, Yukinari; Mimura, Masaaki; Shimada, Hirotnitsu; Kai, Fumiaki; Matsumoto, Naohide.

In: Bulletin of the Chemical Society of Japan, Vol. 71, No. 1, 01.1998, p. 167-173.

Research output: Contribution to journalArticle

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abstract = "Potassium salts of cobalt(III) and manganese(III) complexes, K[CoL(py)2]·2EtOH·MeOH 1 and K[MnL(py)2]·py 2, have been prepared, where H4L= 1,2-bis(hydroxybenzamido)benzene and py = pyridine. 1 crystallizes in the monoclinic space group P21/n with the cell dimensions of a= 12.688(3), b= 17.555(4), c= 16.673(3) {\AA}, β = 102.59(2)°, V= 3624(1) ̊3 and Z = 4, in which potassium ion plays a role of connector for two adjacent [CoL(py)2]- molecules through K-O interaction (two phenoxo oxygen atoms of a cobalt(III) complex, two oxygen atoms of the solvent molecules, and an amido oxygen of the adjacent unit) to give an extended one-dimensional structure. 2 crystallizes in the orthorhombic space group P212121 with the cell dimensions of a= 14.358(1), b= 16.457(2), c= 13.703(2) {\AA}3, V = 3237.7(5) {\AA}3 and Z = 4, in which potassium ion plays a role of connector for three adjacent [MnL(py)2]- molecules through K-O interaction to give an extended three-dimensional structure.",
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