Motions of Ethylammonium Ions in Solid Ethylammonium Chloranilate Studied by 1H Nuclear Magnetic Resonance

Hiroyuki Ishida, Naoki Kumagae, Setsuko Sato

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The motions of the ethylammonium ion in solid ethylammonium chloranilate, C2H5NH3 QHO4CI2, are studied by ‘h NMR second moment (M2) and spin-lattice relaxation time (Ji) measurements. Reorientations of the CH3 group about the C-C bond axis and the NH3 group about C-N bond axis were observed and their motional parameters were evaluated. The internal rotational barriers of the CH3 and NH3 groups of an isolated C2H5NH3 ion were estimated from ab initio molecular orbital calculations.

Original languageEnglish
Pages (from-to)523-526
Number of pages4
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume56
Issue number6-7
DOIs
Publication statusPublished - Jul 2001

Keywords

  • Ethylammonium Ion
  • HF
  • Molecular Motion
  • Nuclear Magnetic Resonance

ASJC Scopus subject areas

  • Mathematical Physics
  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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