Morphology assisted exchange reaction of poly(p-oxybenzoyl-co-p- mercaptobenzoyl)

Yukio Fujiwara, Shin Ichiro Kohama, Shinichi Yamazaki, Kumio Kimura

Research output: Contribution to conferencePaper

Abstract

Poly(p-oxyberizoyi-co-p-mercaptobenzoyl) (POB-co-PMB) needle-like crystals containing 7 mol%; p-oxybenzoyl (OB) unit were converted to poly(p-oxybenzoyl) crystals by heat treatment with S-acety W-marcaptobenzoic acid in an aromatic solvent via ester-thioester exchange reaction with reorganizing the super-structure. The morphology changed from needle to fish-bone while p-mercaptobenzoyl moiety was excluded from the crystals. When POB-co-PMB needle-like crystals containing 64 mol% OB unit was heat-treated withp-acetoxybenzoic acid, the content of OB unit increased to 89 mol% with maintaining the needle-like morphology. p-Mercaptobenzoyl unit in the crystals prepared in the middle copolymerization ratio was replaced by OB unit via exchange reactions between solid and liquid phases under the guidance of super-structure.

Original languageEnglish
Number of pages1
Publication statusPublished - Oct 18 2006
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period5/24/065/26/06

Keywords

  • Morphology
  • Poly(p-oxyberizoyi-co-p-mercaptobenzoyl)
  • Transesterification
  • Whisker

ASJC Scopus subject areas

  • Engineering(all)

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    Fujiwara, Y., Kohama, S. I., Yamazaki, S., & Kimura, K. (2006). Morphology assisted exchange reaction of poly(p-oxybenzoyl-co-p- mercaptobenzoyl). Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.