Abstract
Poly(p-oxyberizoyi-co-p-mercaptobenzoyl) (POB-co-PMB) needle-like crystals containing 7 mol%; p-oxybenzoyl (OB) unit were converted to poly(p-oxybenzoyl) crystals by heat treatment with S-acety W-marcaptobenzoic acid in an aromatic solvent via ester-thioester exchange reaction with reorganizing the super-structure. The morphology changed from needle to fish-bone while p-mercaptobenzoyl moiety was excluded from the crystals. When POB-co-PMB needle-like crystals containing 64 mol% OB unit was heat-treated withp-acetoxybenzoic acid, the content of OB unit increased to 89 mol% with maintaining the needle-like morphology. p-Mercaptobenzoyl unit in the crystals prepared in the middle copolymerization ratio was replaced by OB unit via exchange reactions between solid and liquid phases under the guidance of super-structure.
| Original language | English |
|---|---|
| Title of host publication | Polymer Preprints, Japan |
| Pages | 672 |
| Number of pages | 1 |
| Volume | 55 |
| Edition | 1 |
| Publication status | Published - 2006 |
| Event | 55th SPSJ Annual Meeting - Nagoya, Japan Duration: May 24 2006 → May 26 2006 |
Other
| Other | 55th SPSJ Annual Meeting |
|---|---|
| Country | Japan |
| City | Nagoya |
| Period | 5/24/06 → 5/26/06 |
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Keywords
- Morphology
- Poly(p-oxyberizoyi-co-p-mercaptobenzoyl)
- Transesterification
- Whisker
ASJC Scopus subject areas
- Engineering(all)
Cite this
Morphology assisted exchange reaction of poly(p-oxybenzoyl-co-p- mercaptobenzoyl). / Fujiwara, Yukio; Kohama, Shin Ichiro; Yamazaki, Shinichi; Kimura, Kunio.
Polymer Preprints, Japan. Vol. 55 1. ed. 2006. p. 672.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Morphology assisted exchange reaction of poly(p-oxybenzoyl-co-p- mercaptobenzoyl)
AU - Fujiwara, Yukio
AU - Kohama, Shin Ichiro
AU - Yamazaki, Shinichi
AU - Kimura, Kunio
PY - 2006
Y1 - 2006
N2 - Poly(p-oxyberizoyi-co-p-mercaptobenzoyl) (POB-co-PMB) needle-like crystals containing 7 mol%; p-oxybenzoyl (OB) unit were converted to poly(p-oxybenzoyl) crystals by heat treatment with S-acety W-marcaptobenzoic acid in an aromatic solvent via ester-thioester exchange reaction with reorganizing the super-structure. The morphology changed from needle to fish-bone while p-mercaptobenzoyl moiety was excluded from the crystals. When POB-co-PMB needle-like crystals containing 64 mol% OB unit was heat-treated withp-acetoxybenzoic acid, the content of OB unit increased to 89 mol% with maintaining the needle-like morphology. p-Mercaptobenzoyl unit in the crystals prepared in the middle copolymerization ratio was replaced by OB unit via exchange reactions between solid and liquid phases under the guidance of super-structure.
AB - Poly(p-oxyberizoyi-co-p-mercaptobenzoyl) (POB-co-PMB) needle-like crystals containing 7 mol%; p-oxybenzoyl (OB) unit were converted to poly(p-oxybenzoyl) crystals by heat treatment with S-acety W-marcaptobenzoic acid in an aromatic solvent via ester-thioester exchange reaction with reorganizing the super-structure. The morphology changed from needle to fish-bone while p-mercaptobenzoyl moiety was excluded from the crystals. When POB-co-PMB needle-like crystals containing 64 mol% OB unit was heat-treated withp-acetoxybenzoic acid, the content of OB unit increased to 89 mol% with maintaining the needle-like morphology. p-Mercaptobenzoyl unit in the crystals prepared in the middle copolymerization ratio was replaced by OB unit via exchange reactions between solid and liquid phases under the guidance of super-structure.
KW - Morphology
KW - Poly(p-oxyberizoyi-co-p-mercaptobenzoyl)
KW - Transesterification
KW - Whisker
UR - http://www.scopus.com/inward/record.url?scp=33749657485&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33749657485&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:33749657485
VL - 55
SP - 672
BT - Polymer Preprints, Japan
ER -