Molecular structure and spectroscopic properties of [Co(Me 2dtc)2{(Ph2PO)2BF2}] (Me2dtc = N,N-dimethyldithiocarbamate)

Kyohei Sakano; Syohei Yamaguchi; Takayoshi Suzuki; Yukinari Sunatsuki; Masaaki Kojima; Kazuo Kashiwabara

doi:10.1016/j.ica.2013.10.028

Molecular structure and spectroscopic properties of [Co(Me ₂dtc)₂{(Ph₂PO)₂BF₂}] (Me₂dtc = N,N-dimethyldithiocarbamate)

Kyohei Sakano, Syohei Yamaguchi, Takayoshi Suzuki, Yukinari Sunatsuki, Masaaki Kojima, Kazuo Kashiwabara

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Oxidation of a blue ethanolic mixture containing Co(BF₄) ₂·6H₂O and PClPh₂ by tetramethylthiuram disulfide afforded a red-colored complex having a cis-[Co^III(Me ₂dtc)₂(P)₂] environment (Me₂dtc ^- = N,N-dimethyldithiocarbamate), although the yield was relatively low. Single-crystal X-ray crystallography revealed that the product was [Co(Me₂dtc)₂{(Ph₂PO)₂BF ₂}] (1), where bis(diphenylphosphinito)difluoroborate was probably formed by hydrolysis of PClPh₂ followed by reaction with BF ₄^- in ethanol. The same complex was also prepared by hydrolysis of cis-[Co(Me₂dtc)₂(PHPh₂) ₂]BF₄ in a mixture of acetonitrile, methanol and water. The molecular structure and spectroscopic properties of complex 1 were compared with those of the corresponding Ph₂POMe complex, cis-[Co(Me ₂dtc)₂(Ph₂POMe)₂]BF₄.

Original language	English
Pages (from-to)	122-125
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	410
DOIs	https://doi.org/10.1016/j.ica.2013.10.028
Publication status	Published - Jan 30 2014

Keywords

(Phosphinito)borate
Chlorodiphenylphosphine
Cobalt(III)
Crystal structure
Dithiocarbamate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{667174778e394db4ac797460ed523441,

title = "Molecular structure and spectroscopic properties of [Co(Me 2dtc)2{(Ph2PO)2BF2}] (Me2dtc = N,N-dimethyldithiocarbamate)",

abstract = "Oxidation of a blue ethanolic mixture containing Co(BF4) 2·6H2O and PClPh2 by tetramethylthiuram disulfide afforded a red-colored complex having a cis-[CoIII(Me 2dtc)2(P)2] environment (Me2dtc - = N,N-dimethyldithiocarbamate), although the yield was relatively low. Single-crystal X-ray crystallography revealed that the product was [Co(Me2dtc)2{(Ph2PO)2BF 2}] (1), where bis(diphenylphosphinito)difluoroborate was probably formed by hydrolysis of PClPh2 followed by reaction with BF 4- in ethanol. The same complex was also prepared by hydrolysis of cis-[Co(Me2dtc)2(PHPh2) 2]BF4 in a mixture of acetonitrile, methanol and water. The molecular structure and spectroscopic properties of complex 1 were compared with those of the corresponding Ph2POMe complex, cis-[Co(Me 2dtc)2(Ph2POMe)2]BF4.",

keywords = "(Phosphinito)borate, Chlorodiphenylphosphine, Cobalt(III), Crystal structure, Dithiocarbamate",

author = "Kyohei Sakano and Syohei Yamaguchi and Takayoshi Suzuki and Yukinari Sunatsuki and Masaaki Kojima and Kazuo Kashiwabara",

note = "Funding Information: This work was partly supported by a Grant-in-Aids for Scientific Research Nos. 23655052 and 25410070 from the Ministry of Education, Culture, Sports, Science, and Technology , Japan. ",

year = "2014",

month = jan,

day = "30",

doi = "10.1016/j.ica.2013.10.028",

language = "English",

volume = "410",

pages = "122--125",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Molecular structure and spectroscopic properties of [Co(Me 2dtc)2{(Ph2PO)2BF2}] (Me2dtc = N,N-dimethyldithiocarbamate)

AU - Sakano, Kyohei

AU - Yamaguchi, Syohei

AU - Suzuki, Takayoshi

AU - Sunatsuki, Yukinari

AU - Kojima, Masaaki

AU - Kashiwabara, Kazuo

N1 - Funding Information: This work was partly supported by a Grant-in-Aids for Scientific Research Nos. 23655052 and 25410070 from the Ministry of Education, Culture, Sports, Science, and Technology , Japan.

PY - 2014/1/30

Y1 - 2014/1/30

N2 - Oxidation of a blue ethanolic mixture containing Co(BF4) 2·6H2O and PClPh2 by tetramethylthiuram disulfide afforded a red-colored complex having a cis-[CoIII(Me 2dtc)2(P)2] environment (Me2dtc - = N,N-dimethyldithiocarbamate), although the yield was relatively low. Single-crystal X-ray crystallography revealed that the product was [Co(Me2dtc)2{(Ph2PO)2BF 2}] (1), where bis(diphenylphosphinito)difluoroborate was probably formed by hydrolysis of PClPh2 followed by reaction with BF 4- in ethanol. The same complex was also prepared by hydrolysis of cis-[Co(Me2dtc)2(PHPh2) 2]BF4 in a mixture of acetonitrile, methanol and water. The molecular structure and spectroscopic properties of complex 1 were compared with those of the corresponding Ph2POMe complex, cis-[Co(Me 2dtc)2(Ph2POMe)2]BF4.

AB - Oxidation of a blue ethanolic mixture containing Co(BF4) 2·6H2O and PClPh2 by tetramethylthiuram disulfide afforded a red-colored complex having a cis-[CoIII(Me 2dtc)2(P)2] environment (Me2dtc - = N,N-dimethyldithiocarbamate), although the yield was relatively low. Single-crystal X-ray crystallography revealed that the product was [Co(Me2dtc)2{(Ph2PO)2BF 2}] (1), where bis(diphenylphosphinito)difluoroborate was probably formed by hydrolysis of PClPh2 followed by reaction with BF 4- in ethanol. The same complex was also prepared by hydrolysis of cis-[Co(Me2dtc)2(PHPh2) 2]BF4 in a mixture of acetonitrile, methanol and water. The molecular structure and spectroscopic properties of complex 1 were compared with those of the corresponding Ph2POMe complex, cis-[Co(Me 2dtc)2(Ph2POMe)2]BF4.

KW - (Phosphinito)borate

KW - Chlorodiphenylphosphine

KW - Cobalt(III)

KW - Crystal structure

KW - Dithiocarbamate

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U2 - 10.1016/j.ica.2013.10.028

DO - 10.1016/j.ica.2013.10.028

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VL - 410

SP - 122

EP - 125

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

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