Molecular recognition: New chiral metalloporphyrins as receptor models

Hisanobu Ogoshi; Tadashi Ema; Yusuke Kato; Tadashi Mizutani; Yasuhisa Kuroda

doi:10.1080/10610279508032527

Molecular recognition: New chiral metalloporphyrins as receptor models

Hisanobu Ogoshi, Tadashi Ema, Yusuke Kato, Tadashi Mizutani, Yasuhisa Kuroda

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

New chiral metalloporphyrins capable of multi-point recognition are prepared and their recognition behavior, especially chiral recognition, is studied. The first part of the paper is concerned with general formalism for multi-point recognition, where uniqueness of multi-point recognition, isolation of interaction in terms of free energy, enthalpy and entropy, and the meaning of these thermodynamic parameters are discussed. Enantioselective binding of amino acid esters to two new chiral porphyrins is investigated by UV-vis, NMR and IR spectroscopic methods. Chiral recognition is achieved by combination of three recognition interactions between host and guest.

Original language	English
Pages (from-to)	115-124
Number of pages	10
Journal	Supramolecular Chemistry
Volume	6
Issue number	1-2
DOIs	https://doi.org/10.1080/10610279508032527
Publication status	Published - Oct 1995
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Molecular recognition: New chiral metalloporphyrins as receptor models",

abstract = "New chiral metalloporphyrins capable of multi-point recognition are prepared and their recognition behavior, especially chiral recognition, is studied. The first part of the paper is concerned with general formalism for multi-point recognition, where uniqueness of multi-point recognition, isolation of interaction in terms of free energy, enthalpy and entropy, and the meaning of these thermodynamic parameters are discussed. Enantioselective binding of amino acid esters to two new chiral porphyrins is investigated by UV-vis, NMR and IR spectroscopic methods. Chiral recognition is achieved by combination of three recognition interactions between host and guest.",

author = "Hisanobu Ogoshi and Tadashi Ema and Yusuke Kato and Tadashi Mizutani and Yasuhisa Kuroda",

note = "Funding Information: This work was supported by a Grant-in-Aid for Specially Promoted Research (No. 04101003) from the Ministry of Education, Science, and Culture of Japan.",

year = "1995",

month = oct,

doi = "10.1080/10610279508032527",

language = "English",

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journal = "Supramolecular Chemistry",

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TY - JOUR

T1 - Molecular recognition

T2 - New chiral metalloporphyrins as receptor models

AU - Ogoshi, Hisanobu

AU - Ema, Tadashi

AU - Kato, Yusuke

AU - Mizutani, Tadashi

AU - Kuroda, Yasuhisa

N1 - Funding Information: This work was supported by a Grant-in-Aid for Specially Promoted Research (No. 04101003) from the Ministry of Education, Science, and Culture of Japan.

PY - 1995/10

Y1 - 1995/10

N2 - New chiral metalloporphyrins capable of multi-point recognition are prepared and their recognition behavior, especially chiral recognition, is studied. The first part of the paper is concerned with general formalism for multi-point recognition, where uniqueness of multi-point recognition, isolation of interaction in terms of free energy, enthalpy and entropy, and the meaning of these thermodynamic parameters are discussed. Enantioselective binding of amino acid esters to two new chiral porphyrins is investigated by UV-vis, NMR and IR spectroscopic methods. Chiral recognition is achieved by combination of three recognition interactions between host and guest.

AB - New chiral metalloporphyrins capable of multi-point recognition are prepared and their recognition behavior, especially chiral recognition, is studied. The first part of the paper is concerned with general formalism for multi-point recognition, where uniqueness of multi-point recognition, isolation of interaction in terms of free energy, enthalpy and entropy, and the meaning of these thermodynamic parameters are discussed. Enantioselective binding of amino acid esters to two new chiral porphyrins is investigated by UV-vis, NMR and IR spectroscopic methods. Chiral recognition is achieved by combination of three recognition interactions between host and guest.

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Molecular recognition: New chiral metalloporphyrins as receptor models

Abstract

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