Molecular Dynamics Study of Kinetic Hydrate Inhibitors: The Optimal Inhibitor Size and Effect of Guest Species

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

We propose a model for slowing down of clathrate hydrate formation caused by kinetic hydrate inhibitors (KHIs) on the basis of the Gibbs-Thomson effect. The residence time of inhibitor molecules bound to the hydrate surface and the intrinsic growth rate of the clathrate hydrate without KHIs are key ingredients of the model. The binding free energies of the monomer, dimer, tetramer, and octamer of a KHI, polyvinylcaprolactam (PVCap), are calculated using molecular dynamics simulations to estimate the residence times, which are far beyond the feasible simulation time. Our model accounts for the kinetic inhibition mechanism while reproducing experimental data of the size dependence of PVCap very well. We demonstrate that this model explains why blends of high and low-molecular-weight polymers show better performance than the KHI with a unimodal molecular weight distribution and why quaternary ammonium cations are good KHIs for tetrahydrofuran hydrate although they cannot inhibit formation of natural gas hydrates.

Original languageEnglish
Pages (from-to)1806-1816
Number of pages11
JournalJournal of Physical Chemistry C
Volume123
Issue number3
DOIs
Publication statusPublished - Jan 24 2019

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Fingerprint Dive into the research topics of 'Molecular Dynamics Study of Kinetic Hydrate Inhibitors: The Optimal Inhibitor Size and Effect of Guest Species'. Together they form a unique fingerprint.

  • Cite this