Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes

Yutaka Takaguchi, H. Fujihara, N. Furukawa

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO2] were prepared and variable-temperature 1H NMR studies revealed that these telluranes were composed of the sterically congested rotamers. The first examples of the activation parameters for rotation of the TeC bonds were obtained in D NMR experiments.

Original languageEnglish
Pages (from-to)49-52
Number of pages4
JournalJournal of Organometallic Chemistry
Volume498
Issue number1
Publication statusPublished - Aug 9 1995
Externally publishedYes

Fingerprint

Halogens
Molecular Dynamics Simulation
Molecular dynamics
Nuclear magnetic resonance
molecular dynamics
nuclear magnetic resonance
Temperature
halogens
Chemical activation
activation
Experiments
temperature
Proton Magnetic Resonance Spectroscopy

Keywords

  • Chalcogen
  • Dynamics
  • Group 16
  • Hindered ligands
  • Nuclear magnetic resonances
  • Tellurium

ASJC Scopus subject areas

  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

Cite this

Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes. / Takaguchi, Yutaka; Fujihara, H.; Furukawa, N.

In: Journal of Organometallic Chemistry, Vol. 498, No. 1, 09.08.1995, p. 49-52.

Research output: Contribution to journalArticle

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