Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes

Y. Takaguchi, H. Fujihara, N. Furukawa

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO2] were prepared and variable-temperature 1H NMR studies revealed that these telluranes were composed of the sterically congested rotamers. The first examples of the activation parameters for rotation of the TeC bonds were obtained in D NMR experiments.

Original languageEnglish
Pages (from-to)49-52
Number of pages4
JournalJournal of Organometallic Chemistry
Volume498
Issue number1
DOIs
Publication statusPublished - Aug 9 1995
Externally publishedYes

Keywords

  • Chalcogen
  • Dynamics
  • Group 16
  • Hindered ligands
  • Nuclear magnetic resonances
  • Tellurium

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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