Mixed-valence TTF intercalated in lamellar MnPS3 crystals

T. Miyazaki, S. Matsuzaki, K. Ichimura, M. Sano

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

TTF species intercalated in van der Waals gaps of MnPS3 single crystals were found to be in the state of mixed-valence, and their degree of ionicity was estimated at 0.8 from the Raman band observed at 1432 cm-1. The frequency difference between the Raman band and the IR band of the same origin, of which IR intensity was enhanced through the vibronic intensity borrowing from the charge-transfer transitions, amounts to 120 cm-1. This amount of frequency difference suggests that the intermolecular interaction between TTF species confined in MnPS3 is stronger than that in TTF radical-salt crystals.

Original languageEnglish
Pages (from-to)949-951
Number of pages3
JournalSolid State Communications
Volume85
Issue number11
DOIs
Publication statusPublished - Mar 1993
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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