Mineral chemistry of schulenbergite and its Zn-dominant analogue from the Hirao mine, Osaka, Japan

Masayuki Ohnishi, Isao Kusachi, Shoichi Kobayashi, Junji Yamakawa

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Schulenbergite and its Zn-dominant analogue occur in the Hirao mine, Osaka Prefecture, Japan. The minerals were found as crusts on the same gallery wall and in cracks of altered shale. The minerals occur as aggregates of hexagonal platy crystals up to 0.5 mm across and 0.05 mm thick. The schulenbergite is greenish blue to blue-green in color, and the Cu/(Cu + Zn) molar ratio varies from 0.67 to 0.42. The Zn-dominant analogue of schulenbergite is pale blue in color, and the Cu/(Cu + Zn) molar ratio varies from 0.30 to 0.21. The average unit cell parameters of schulenbergite and its Zn-dominant analogue calculated from the X-ray powder diffraction data were: a = 8.256 (2) and c = 7.207 (3) Å, and a = 8.292 (2) and c = 7.271 (4) Å, respectively. It is likely that schulenbergite and its Zn-dominant analogue from the Hirao mine were formed as secondary minerals from Cu and Zn ion-bearing solution that were derived from chalcopyrite and sphalerite in the host rock.

Original languageEnglish
Pages (from-to)233-239
Number of pages7
JournalJournal of Mineralogical and Petrological Sciences
Volume102
Issue number4
DOIs
Publication statusPublished - Sep 5 2007

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Japan
minerals
chemistry
analogs
secondary mineral
mineral
sphalerite
chalcopyrite
host rock
shale
crack
X-ray diffraction
crystal
crust
color
ion
zincblende
crusts
cracks
rocks

Keywords

  • Hirao mine
  • Japan
  • Osaka
  • Schulenbergite
  • Zn-dominant analogue

ASJC Scopus subject areas

  • Geophysics
  • Geology

Cite this

Mineral chemistry of schulenbergite and its Zn-dominant analogue from the Hirao mine, Osaka, Japan. / Ohnishi, Masayuki; Kusachi, Isao; Kobayashi, Shoichi; Yamakawa, Junji.

In: Journal of Mineralogical and Petrological Sciences, Vol. 102, No. 4, 05.09.2007, p. 233-239.

Research output: Contribution to journalArticle

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AB - Schulenbergite and its Zn-dominant analogue occur in the Hirao mine, Osaka Prefecture, Japan. The minerals were found as crusts on the same gallery wall and in cracks of altered shale. The minerals occur as aggregates of hexagonal platy crystals up to 0.5 mm across and 0.05 mm thick. The schulenbergite is greenish blue to blue-green in color, and the Cu/(Cu + Zn) molar ratio varies from 0.67 to 0.42. The Zn-dominant analogue of schulenbergite is pale blue in color, and the Cu/(Cu + Zn) molar ratio varies from 0.30 to 0.21. The average unit cell parameters of schulenbergite and its Zn-dominant analogue calculated from the X-ray powder diffraction data were: a = 8.256 (2) and c = 7.207 (3) Å, and a = 8.292 (2) and c = 7.271 (4) Å, respectively. It is likely that schulenbergite and its Zn-dominant analogue from the Hirao mine were formed as secondary minerals from Cu and Zn ion-bearing solution that were derived from chalcopyrite and sphalerite in the host rock.

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