Microscopic conduction behavior analysis on ZrO2-based ion conductors by wideband conductivity measurement

Takashi Teranishi; Kosuke Shimizu; Hidetaka Hayashi; Akira Kishimoto

doi:10.4028/www.scientific.net/KEM.566.141

Microscopic conduction behavior analysis on ZrO₂-based ion conductors by wideband conductivity measurement

Takashi Teranishi, Kosuke Shimizu, Hidetaka Hayashi, Akira Kishimoto

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

All contributions to the total conductivity, electrolyte-electrode interfaces, grain boundaries, ion-hopping, and optical phonons, were determined on the 8 mol% yttria-stabilized zirconia (8YSZ) and 8 mol% ytterbia-stabilized zirconia (8YbSZ) ceramics using the wideband conductivity spectroscopy. Complex conductivity spectra from 10^-1 Hz to 10¹⁴ Hz were successfully obtained. The higher total conductivity of the 8YbSZ ceramics compared to the 8YSZ in wideband frequencies was mainly attributed to difference in the DC conductivity due to universal dielectric response (UDR), σ_dc; σ_dc _(8YbSZ) > σ_dc _(8YSZ). Other parameters in the UDR and the optical phonon parameters did not greatly influence on the difference in their intrinsic conductivities.

Original language	English
Title of host publication	Electroceramics in Japan XV
Publisher	Trans Tech Publications Ltd
Pages	141-144
Number of pages	4
ISBN (Print)	9783037857618
DOIs	https://doi.org/10.4028/www.scientific.net/KEM.566.141
Publication status	Published - 2013
Event	31st Electronics Division Meeting of the Ceramic Society of Japan - Tokyo, Japan Duration: Oct 28 2011 → Oct 29 2011

Publication series

Name	Key Engineering Materials
Volume	566
ISSN (Print)	1013-9826
ISSN (Electronic)	1662-9795

Other

Other	31st Electronics Division Meeting of the Ceramic Society of Japan
Country/Territory	Japan
City	Tokyo
Period	10/28/11 → 10/29/11

Keywords

Conductivity spectroscopy
Optical phonon modes
Universal dielectric response

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

Access to Document

10.4028/www.scientific.net/KEM.566.141

Cite this

Microscopic conduction behavior analysis on ZrO₂-based ion conductors by wideband conductivity measurement. / Teranishi, Takashi; Shimizu, Kosuke; Hayashi, Hidetaka; Kishimoto, Akira.

Electroceramics in Japan XV. Trans Tech Publications Ltd, 2013. p. 141-144 (Key Engineering Materials; Vol. 566).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Teranishi, T, Shimizu, K, Hayashi, H & Kishimoto, A 2013, Microscopic conduction behavior analysis on ZrO₂-based ion conductors by wideband conductivity measurement. in Electroceramics in Japan XV. Key Engineering Materials, vol. 566, Trans Tech Publications Ltd, pp. 141-144, 31st Electronics Division Meeting of the Ceramic Society of Japan, Tokyo, Japan, 10/28/11. https://doi.org/10.4028/www.scientific.net/KEM.566.141

@inproceedings{a86c54a53ed144d082e242756569dc4e,

title = "Microscopic conduction behavior analysis on ZrO2-based ion conductors by wideband conductivity measurement",

abstract = "All contributions to the total conductivity, electrolyte-electrode interfaces, grain boundaries, ion-hopping, and optical phonons, were determined on the 8 mol% yttria-stabilized zirconia (8YSZ) and 8 mol% ytterbia-stabilized zirconia (8YbSZ) ceramics using the wideband conductivity spectroscopy. Complex conductivity spectra from 10-1 Hz to 1014 Hz were successfully obtained. The higher total conductivity of the 8YbSZ ceramics compared to the 8YSZ in wideband frequencies was mainly attributed to difference in the DC conductivity due to universal dielectric response (UDR), σdc; σdc (8YbSZ) > σdc (8YSZ). Other parameters in the UDR and the optical phonon parameters did not greatly influence on the difference in their intrinsic conductivities.",

keywords = "Conductivity spectroscopy, Optical phonon modes, Universal dielectric response",

author = "Takashi Teranishi and Kosuke Shimizu and Hidetaka Hayashi and Akira Kishimoto",

year = "2013",

doi = "10.4028/www.scientific.net/KEM.566.141",

language = "English",

isbn = "9783037857618",

series = "Key Engineering Materials",

publisher = "Trans Tech Publications Ltd",

pages = "141--144",

booktitle = "Electroceramics in Japan XV",

}

TY - GEN

T1 - Microscopic conduction behavior analysis on ZrO2-based ion conductors by wideband conductivity measurement

AU - Teranishi, Takashi

AU - Shimizu, Kosuke

AU - Hayashi, Hidetaka

AU - Kishimoto, Akira

PY - 2013

Y1 - 2013

N2 - All contributions to the total conductivity, electrolyte-electrode interfaces, grain boundaries, ion-hopping, and optical phonons, were determined on the 8 mol% yttria-stabilized zirconia (8YSZ) and 8 mol% ytterbia-stabilized zirconia (8YbSZ) ceramics using the wideband conductivity spectroscopy. Complex conductivity spectra from 10-1 Hz to 1014 Hz were successfully obtained. The higher total conductivity of the 8YbSZ ceramics compared to the 8YSZ in wideband frequencies was mainly attributed to difference in the DC conductivity due to universal dielectric response (UDR), σdc; σdc (8YbSZ) > σdc (8YSZ). Other parameters in the UDR and the optical phonon parameters did not greatly influence on the difference in their intrinsic conductivities.

AB - All contributions to the total conductivity, electrolyte-electrode interfaces, grain boundaries, ion-hopping, and optical phonons, were determined on the 8 mol% yttria-stabilized zirconia (8YSZ) and 8 mol% ytterbia-stabilized zirconia (8YbSZ) ceramics using the wideband conductivity spectroscopy. Complex conductivity spectra from 10-1 Hz to 1014 Hz were successfully obtained. The higher total conductivity of the 8YbSZ ceramics compared to the 8YSZ in wideband frequencies was mainly attributed to difference in the DC conductivity due to universal dielectric response (UDR), σdc; σdc (8YbSZ) > σdc (8YSZ). Other parameters in the UDR and the optical phonon parameters did not greatly influence on the difference in their intrinsic conductivities.

KW - Conductivity spectroscopy

KW - Optical phonon modes

KW - Universal dielectric response

UR - http://www.scopus.com/inward/record.url?scp=84883497825&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84883497825&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/KEM.566.141

DO - 10.4028/www.scientific.net/KEM.566.141

M3 - Conference contribution

AN - SCOPUS:84883497825

SN - 9783037857618

T3 - Key Engineering Materials

SP - 141

EP - 144

BT - Electroceramics in Japan XV

PB - Trans Tech Publications Ltd

T2 - 31st Electronics Division Meeting of the Ceramic Society of Japan

Y2 - 28 October 2011 through 29 October 2011

ER -