Micro-X-ray absorption near edge structure determination of Fe3+/ΣFe in omphacite inclusion within garnet from Dabie eclogite, East-Central China

Masaru Terabayashi, Takashi Matsui, Kazuaki Okamoto, Hiroaki Ozawa, Yoshiyuki Kaneko, Shigenori Maruyama

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Abstract: The Fe K-edge micro-X-ray absorption near edge structure (XANES) spectra of omphacite included within garnet from the Dabie eclogites, east-central China, were measured to estimate the oxidation state of iron in omphacite. The micro-XANES analyses of omphacite inclusions within garnet yield higher Fe3+/ΣFe ratios of 0.18 to 0.59 than those of 0.00 to 0.31 calculated by charge balance from electron microprobe analyses. The estimated temperatures of garnet-clinopyroxene pairs from 10 eclogites using Fe3+ and Fe2+ contents calculated by charge balance are 603 to 1078°C except one sample. The temperatures calculated using micro-XANES-measured Fe3+ and Fe2+ contents are 530-918°C except one sample. Along the north-south cross-section in the study area, the estimated temperatures based on the charge balance calculation of Fe3+ tend to be identical or higher than temperatures estimated based on the calculation of Fe3+ using the XANES technique. Seven of the micro-XANES measurements give approximate temperatures from 500°C to 700°C, and three of the measurements give temperatures of more than 800°C. Those three samples contain higher XGrs corresponding to the distribution coefficient of garnet-clinopyroxene pairs. The pressure and temperature results estimated by the garnet-clinopyroxene-phengite geothermobarometers are mostly in subsolidus conditions, suggesting that there is no extensive melting in eclogite. The present study represents a new temperature calibration based on Fe3+ estimates in omphacite inclusion within garnet based on the XANES analysis, which is taken into account.

Original languageEnglish
Pages (from-to)37-50
Number of pages14
JournalIsland Arc
Volume22
Issue number1
DOIs
Publication statusPublished - Mar 2013
Externally publishedYes

Fingerprint

omphacite
eclogite
garnet
clinopyroxene
temperature
phengite
electron probe analysis
melting
cross section
calibration
oxidation
iron

Keywords

  • Dabie
  • Eclogite
  • Micro-XANES
  • Omphacite inclusion
  • Ultrahigh-pressure

ASJC Scopus subject areas

  • Geology

Cite this

Micro-X-ray absorption near edge structure determination of Fe3+/ΣFe in omphacite inclusion within garnet from Dabie eclogite, East-Central China. / Terabayashi, Masaru; Matsui, Takashi; Okamoto, Kazuaki; Ozawa, Hiroaki; Kaneko, Yoshiyuki; Maruyama, Shigenori.

In: Island Arc, Vol. 22, No. 1, 03.2013, p. 37-50.

Research output: Contribution to journalArticle

Terabayashi, Masaru ; Matsui, Takashi ; Okamoto, Kazuaki ; Ozawa, Hiroaki ; Kaneko, Yoshiyuki ; Maruyama, Shigenori. / Micro-X-ray absorption near edge structure determination of Fe3+/ΣFe in omphacite inclusion within garnet from Dabie eclogite, East-Central China. In: Island Arc. 2013 ; Vol. 22, No. 1. pp. 37-50.
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abstract = "Abstract: The Fe K-edge micro-X-ray absorption near edge structure (XANES) spectra of omphacite included within garnet from the Dabie eclogites, east-central China, were measured to estimate the oxidation state of iron in omphacite. The micro-XANES analyses of omphacite inclusions within garnet yield higher Fe3+/ΣFe ratios of 0.18 to 0.59 than those of 0.00 to 0.31 calculated by charge balance from electron microprobe analyses. The estimated temperatures of garnet-clinopyroxene pairs from 10 eclogites using Fe3+ and Fe2+ contents calculated by charge balance are 603 to 1078°C except one sample. The temperatures calculated using micro-XANES-measured Fe3+ and Fe2+ contents are 530-918°C except one sample. Along the north-south cross-section in the study area, the estimated temperatures based on the charge balance calculation of Fe3+ tend to be identical or higher than temperatures estimated based on the calculation of Fe3+ using the XANES technique. Seven of the micro-XANES measurements give approximate temperatures from 500°C to 700°C, and three of the measurements give temperatures of more than 800°C. Those three samples contain higher XGrs corresponding to the distribution coefficient of garnet-clinopyroxene pairs. The pressure and temperature results estimated by the garnet-clinopyroxene-phengite geothermobarometers are mostly in subsolidus conditions, suggesting that there is no extensive melting in eclogite. The present study represents a new temperature calibration based on Fe3+ estimates in omphacite inclusion within garnet based on the XANES analysis, which is taken into account.",
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AB - Abstract: The Fe K-edge micro-X-ray absorption near edge structure (XANES) spectra of omphacite included within garnet from the Dabie eclogites, east-central China, were measured to estimate the oxidation state of iron in omphacite. The micro-XANES analyses of omphacite inclusions within garnet yield higher Fe3+/ΣFe ratios of 0.18 to 0.59 than those of 0.00 to 0.31 calculated by charge balance from electron microprobe analyses. The estimated temperatures of garnet-clinopyroxene pairs from 10 eclogites using Fe3+ and Fe2+ contents calculated by charge balance are 603 to 1078°C except one sample. The temperatures calculated using micro-XANES-measured Fe3+ and Fe2+ contents are 530-918°C except one sample. Along the north-south cross-section in the study area, the estimated temperatures based on the charge balance calculation of Fe3+ tend to be identical or higher than temperatures estimated based on the calculation of Fe3+ using the XANES technique. Seven of the micro-XANES measurements give approximate temperatures from 500°C to 700°C, and three of the measurements give temperatures of more than 800°C. Those three samples contain higher XGrs corresponding to the distribution coefficient of garnet-clinopyroxene pairs. The pressure and temperature results estimated by the garnet-clinopyroxene-phengite geothermobarometers are mostly in subsolidus conditions, suggesting that there is no extensive melting in eclogite. The present study represents a new temperature calibration based on Fe3+ estimates in omphacite inclusion within garnet based on the XANES analysis, which is taken into account.

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