Metal-intercalated aromatic hydrocarbons: A new class of carbon-based superconductors

Yoshihiro Kubozono, Hiroki Mitamura, Xuesong Lee, Xuexia He, Yusuke Yamanari, Yosuke Takahashi, Yuta Suzuki, Yumiko Kaji, Ritsuko Eguchi, Koki Akaike, Takashi Kambe, Hideki Okamoto, Akihiko Fujiwara, Takashi Kato, Taichi Kosugi, Hideo Aoki

Research output: Contribution to journalReview article

171 Citations (Scopus)

Abstract

New carbon-based superconductors are synthesized by intercalating metal atoms into the solid-phase hydrocarbons picene and coronene. The highest reported superconducting transition temperature, T c, of a hydrocarbon superconductor is 18 K for K 3picene. The physics and chemistry of the hydrocarbon superconductors are extensively described for A xpicene (A: alkali and alkali earth-metal atoms) for x = 0-5. The theoretical picture of their electronic structure is also reviewed. Future prospects for hydrocarbon superconductors are discussed from the viewpoint of combining electronics with condensed-matter physics: modification of the physical properties of hydrocarbon solids is explored by building them into a field-effect transistor. The features of other carbon-based superconductors are compared to clarify the nature of hydrocarbon superconductors.

Original languageEnglish
Pages (from-to)16476-16493
Number of pages18
JournalPhysical Chemistry Chemical Physics
Volume13
Issue number37
DOIs
Publication statusPublished - Oct 7 2011

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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    Kubozono, Y., Mitamura, H., Lee, X., He, X., Yamanari, Y., Takahashi, Y., Suzuki, Y., Kaji, Y., Eguchi, R., Akaike, K., Kambe, T., Okamoto, H., Fujiwara, A., Kato, T., Kosugi, T., & Aoki, H. (2011). Metal-intercalated aromatic hydrocarbons: A new class of carbon-based superconductors. Physical Chemistry Chemical Physics, 13(37), 16476-16493. https://doi.org/10.1039/c1cp20961b