Material Exhibiting Efficient CO2 Adsorption at Room Temperature for Concentrations Lower Than 1000 ppm: Elucidation of the State of Barium Ion Exchanged in an MFI-Type Zeolite

Atsushi Itadani, Akira Oda, Hiroe Torigoe, Takahiro Ohkubo, Mineo Sato, Hisayoshi Kobayashi, Yasushige Kuroda

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Carbon dioxide (CO2) gas is well-known as a greenhouse gas that leads to global warming. Many efforts have been made to capture CO2 from coal-fired power plants, as well as to reduce the amounts of excess CO2 in the atmosphere to around 400 ppm. However, this is not a simple task, particularly in the lower pressure region than 1000 ppm. This is because the CO2 molecule is chemically stable and has a relatively low reactivity. In the present study, the CO2 adsorption at room temperature on MFI-type zeolites exchanged with alkaline-earth-metal ions, with focus on CO2 concentrations 2, compared with other presented samples, such as the sodium-form and transition-metal ion-exchanged MFI-type zeolites. Ethyne (C2H2) was used as a probe molecule. Analyses were carried out with IR spectroscopy and X-ray absorption, and provided significant information regarding the presence of the M2+-O2--M2+ (M2+: alkaline-earth-metal ion) species formed in the samples. It was subsequently determined that this species acts as a highly efficient site for CO2 adsorption at room temperature under very low pressure, compared to a single M2+ species. A further advantage is that this material can be easily regenerated by a treatment, e.g., through the application of the temperature swing adsorption process, at relatively low temperatures (300-473 K).

Original languageEnglish
Pages (from-to)8821-8833
Number of pages13
JournalACS Applied Materials and Interfaces
Volume8
Issue number13
DOIs
Publication statusPublished - Apr 20 2016

Fingerprint

Zeolites
Barium
Alkaline Earth Metals
Ions
Metal ions
Adsorption
Alkaline earth metals
Acetylene
Temperature
Molecules
Coal
X ray absorption
Global warming
Greenhouse gases
Carbon Dioxide
Transition metals
Infrared spectroscopy
Carbon dioxide
Power plants
Gases

Keywords

  • acetylide species
  • BaMFI
  • CO adsorption at 300 K
  • easy regeneration of the sample
  • fast adsorption
  • M-O-M (M: alkaline-earth-metal ion)

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Material Exhibiting Efficient CO2 Adsorption at Room Temperature for Concentrations Lower Than 1000 ppm : Elucidation of the State of Barium Ion Exchanged in an MFI-Type Zeolite. / Itadani, Atsushi; Oda, Akira; Torigoe, Hiroe; Ohkubo, Takahiro; Sato, Mineo; Kobayashi, Hisayoshi; Kuroda, Yasushige.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 13, 20.04.2016, p. 8821-8833.

Research output: Contribution to journalArticle

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AB - Carbon dioxide (CO2) gas is well-known as a greenhouse gas that leads to global warming. Many efforts have been made to capture CO2 from coal-fired power plants, as well as to reduce the amounts of excess CO2 in the atmosphere to around 400 ppm. However, this is not a simple task, particularly in the lower pressure region than 1000 ppm. This is because the CO2 molecule is chemically stable and has a relatively low reactivity. In the present study, the CO2 adsorption at room temperature on MFI-type zeolites exchanged with alkaline-earth-metal ions, with focus on CO2 concentrations 2, compared with other presented samples, such as the sodium-form and transition-metal ion-exchanged MFI-type zeolites. Ethyne (C2H2) was used as a probe molecule. Analyses were carried out with IR spectroscopy and X-ray absorption, and provided significant information regarding the presence of the M2+-O2--M2+ (M2+: alkaline-earth-metal ion) species formed in the samples. It was subsequently determined that this species acts as a highly efficient site for CO2 adsorption at room temperature under very low pressure, compared to a single M2+ species. A further advantage is that this material can be easily regenerated by a treatment, e.g., through the application of the temperature swing adsorption process, at relatively low temperatures (300-473 K).

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