Magnetic properties of purely organic radical magnets, N-(arylthio)-2,4,6-triarylphenylaminyls: Susceptibility and heat capacity measurements

Yoshio Teki, Koichi Itoh, Yozo Miura, Sinya Kurokawa, Sadaharu Ueno, Atsuhiko Okada, Hirokazu Yamakage, Tatsuo Kobayashi, Kiichi Amaya

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Abstract

The magnetic properties of N-[(dichlorophenyl)thio]-2,4,6-tris(chlorophenyl)phenylaminyl radical crystals are reported. The stable radical crystals of N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylammy (1) and N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(3-chlorophenyl)phenylaminyl (2) have shown one-dimensional ferromagnetic behavior which have described using the Bonner-Fisher model with the large ferromagnetic exchange interaction of J/k B = 14.0 K and J/k B = 5.7 K, respectively. In addition to these ferromagnetic compounds, N-[(3,5-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylaminyl (3) has also shown the ferromagnetic intermolecular exchange interaction of J/k B= 1.8 K. For these crystals, we have carried out low-temperature susceptibility and heat capacity measurements below 2 K. Radical 1 has shown a magnetic phase transition at 0.4 K. The susceptibility in the ordered state, however, shows spinflip transition, indicating antiferromagnetic long range ordering. For the ordered state the interchain interactions are also estimated to be J′/k B = 0.02 K. and J″k/ B = -0.01 K. In order to clarify the electronic structures, ab-initio molecular orbital calculations of their substituted radicals are carried out. The correlation between the magnetic interactions and the electronic structures is discussed.

Original languageEnglish
Pages (from-to)95-102
Number of pages8
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume306
Publication statusPublished - 1997
Externally publishedYes

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Specific heat
Magnets
Magnetic properties
magnets
Exchange interactions
specific heat
magnetic properties
magnetic permeability
Crystals
Electronic structure
Orbital calculations
interactions
Molecular orbitals
electronic structure
crystals
Phase transitions
molecular orbitals
Temperature

ASJC Scopus subject areas

  • Condensed Matter Physics

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Magnetic properties of purely organic radical magnets, N-(arylthio)-2,4,6-triarylphenylaminyls : Susceptibility and heat capacity measurements. / Teki, Yoshio; Itoh, Koichi; Miura, Yozo; Kurokawa, Sinya; Ueno, Sadaharu; Okada, Atsuhiko; Yamakage, Hirokazu; Kobayashi, Tatsuo; Amaya, Kiichi.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 306, 1997, p. 95-102.

Research output: Contribution to journalArticle

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abstract = "The magnetic properties of N-[(dichlorophenyl)thio]-2,4,6-tris(chlorophenyl)phenylaminyl radical crystals are reported. The stable radical crystals of N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylammy (1) and N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(3-chlorophenyl)phenylaminyl (2) have shown one-dimensional ferromagnetic behavior which have described using the Bonner-Fisher model with the large ferromagnetic exchange interaction of J/k B = 14.0 K and J/k B = 5.7 K, respectively. In addition to these ferromagnetic compounds, N-[(3,5-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylaminyl (3) has also shown the ferromagnetic intermolecular exchange interaction of J/k B= 1.8 K. For these crystals, we have carried out low-temperature susceptibility and heat capacity measurements below 2 K. Radical 1 has shown a magnetic phase transition at 0.4 K. The susceptibility in the ordered state, however, shows spinflip transition, indicating antiferromagnetic long range ordering. For the ordered state the interchain interactions are also estimated to be J′/k B = 0.02 K. and J″k/ B = -0.01 K. In order to clarify the electronic structures, ab-initio molecular orbital calculations of their substituted radicals are carried out. The correlation between the magnetic interactions and the electronic structures is discussed.",
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T1 - Magnetic properties of purely organic radical magnets, N-(arylthio)-2,4,6-triarylphenylaminyls

T2 - Susceptibility and heat capacity measurements

AU - Teki, Yoshio

AU - Itoh, Koichi

AU - Miura, Yozo

AU - Kurokawa, Sinya

AU - Ueno, Sadaharu

AU - Okada, Atsuhiko

AU - Yamakage, Hirokazu

AU - Kobayashi, Tatsuo

AU - Amaya, Kiichi

PY - 1997

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N2 - The magnetic properties of N-[(dichlorophenyl)thio]-2,4,6-tris(chlorophenyl)phenylaminyl radical crystals are reported. The stable radical crystals of N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylammy (1) and N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(3-chlorophenyl)phenylaminyl (2) have shown one-dimensional ferromagnetic behavior which have described using the Bonner-Fisher model with the large ferromagnetic exchange interaction of J/k B = 14.0 K and J/k B = 5.7 K, respectively. In addition to these ferromagnetic compounds, N-[(3,5-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylaminyl (3) has also shown the ferromagnetic intermolecular exchange interaction of J/k B= 1.8 K. For these crystals, we have carried out low-temperature susceptibility and heat capacity measurements below 2 K. Radical 1 has shown a magnetic phase transition at 0.4 K. The susceptibility in the ordered state, however, shows spinflip transition, indicating antiferromagnetic long range ordering. For the ordered state the interchain interactions are also estimated to be J′/k B = 0.02 K. and J″k/ B = -0.01 K. In order to clarify the electronic structures, ab-initio molecular orbital calculations of their substituted radicals are carried out. The correlation between the magnetic interactions and the electronic structures is discussed.

AB - The magnetic properties of N-[(dichlorophenyl)thio]-2,4,6-tris(chlorophenyl)phenylaminyl radical crystals are reported. The stable radical crystals of N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylammy (1) and N-[(2,4-dichlorophenyl)thio]-2,4,6-tris(3-chlorophenyl)phenylaminyl (2) have shown one-dimensional ferromagnetic behavior which have described using the Bonner-Fisher model with the large ferromagnetic exchange interaction of J/k B = 14.0 K and J/k B = 5.7 K, respectively. In addition to these ferromagnetic compounds, N-[(3,5-dichlorophenyl)thio]-2,4,6-tris(4-chlorophenyl)phenylaminyl (3) has also shown the ferromagnetic intermolecular exchange interaction of J/k B= 1.8 K. For these crystals, we have carried out low-temperature susceptibility and heat capacity measurements below 2 K. Radical 1 has shown a magnetic phase transition at 0.4 K. The susceptibility in the ordered state, however, shows spinflip transition, indicating antiferromagnetic long range ordering. For the ordered state the interchain interactions are also estimated to be J′/k B = 0.02 K. and J″k/ B = -0.01 K. In order to clarify the electronic structures, ab-initio molecular orbital calculations of their substituted radicals are carried out. The correlation between the magnetic interactions and the electronic structures is discussed.

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