Abstract
The magnetic properties of O 2 adsorbed in the microporous coordination polymer Cd(bpndc)(bpy) were investigated by means of high-field magnetization measurement. The magnetization of adsorbed O 2 has a paramagnetic-like behavior in the low-field region and increases steeply above 50 T. The experiment results suggest that the half of adsorbed O 2 that forms O 2-O 2 dimer causes the metamagnetic-like behavior and the remaining O 2 causes paramagnetic-like behavior owing to nearly isolated spin. A possible arrangement of O 2 is suggested.
| Original language | English |
|---|---|
| Pages (from-to) | 122-125 |
| Number of pages | 4 |
| Journal | Journal of Low Temperature Physics |
| Volume | 159 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Apr 2010 |
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Keywords
- Molecular oxygen
- Spin-dependent intermolecular potential
ASJC Scopus subject areas
- Condensed Matter Physics
- Atomic and Molecular Physics, and Optics
- Materials Science(all)
Cite this
Magnetic properties and the arrangement of molecular oxygen adsorbed in the microporous coordination polymer Cd(bpndc)(bpy). / Hori, A.; Yamaguchi, T.; Kobayashi, Tatsuo; Matsuo, A.; Kindo, K.; Tanaka, D.; Kitagawa, S.
In: Journal of Low Temperature Physics, Vol. 159, No. 1-2, 04.2010, p. 122-125.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Magnetic properties and the arrangement of molecular oxygen adsorbed in the microporous coordination polymer Cd(bpndc)(bpy)
AU - Hori, A.
AU - Yamaguchi, T.
AU - Kobayashi, Tatsuo
AU - Matsuo, A.
AU - Kindo, K.
AU - Tanaka, D.
AU - Kitagawa, S.
PY - 2010/4
Y1 - 2010/4
N2 - The magnetic properties of O 2 adsorbed in the microporous coordination polymer Cd(bpndc)(bpy) were investigated by means of high-field magnetization measurement. The magnetization of adsorbed O 2 has a paramagnetic-like behavior in the low-field region and increases steeply above 50 T. The experiment results suggest that the half of adsorbed O 2 that forms O 2-O 2 dimer causes the metamagnetic-like behavior and the remaining O 2 causes paramagnetic-like behavior owing to nearly isolated spin. A possible arrangement of O 2 is suggested.
AB - The magnetic properties of O 2 adsorbed in the microporous coordination polymer Cd(bpndc)(bpy) were investigated by means of high-field magnetization measurement. The magnetization of adsorbed O 2 has a paramagnetic-like behavior in the low-field region and increases steeply above 50 T. The experiment results suggest that the half of adsorbed O 2 that forms O 2-O 2 dimer causes the metamagnetic-like behavior and the remaining O 2 causes paramagnetic-like behavior owing to nearly isolated spin. A possible arrangement of O 2 is suggested.
KW - Molecular oxygen
KW - Spin-dependent intermolecular potential
UR - http://www.scopus.com/inward/record.url?scp=77950368739&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77950368739&partnerID=8YFLogxK
U2 - 10.1007/s10909-009-0084-8
DO - 10.1007/s10909-009-0084-8
M3 - Article
AN - SCOPUS:77950368739
VL - 159
SP - 122
EP - 125
JO - Journal of Low Temperature Physics
JF - Journal of Low Temperature Physics
SN - 0022-2291
IS - 1-2
ER -