Abstract
The magnetic properties of O 2 adsorbed in the microporous coordination polymer Cd(bpndc)(bpy) were investigated by means of high-field magnetization measurement. The magnetization of adsorbed O 2 has a paramagnetic-like behavior in the low-field region and increases steeply above 50 T. The experiment results suggest that the half of adsorbed O 2 that forms O 2-O 2 dimer causes the metamagnetic-like behavior and the remaining O 2 causes paramagnetic-like behavior owing to nearly isolated spin. A possible arrangement of O 2 is suggested.
| Original language | English |
|---|---|
| Pages (from-to) | 122-125 |
| Number of pages | 4 |
| Journal | Journal of Low Temperature Physics |
| Volume | 159 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Apr 1 2010 |
Keywords
- Molecular oxygen
- Spin-dependent intermolecular potential
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Materials Science(all)
- Condensed Matter Physics
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Hori, A., Yamaguchi, T., Kobayashi, T. C., Matsuo, A., Kindo, K., Tanaka, D., & Kitagawa, S. (2010). Magnetic properties and the arrangement of molecular oxygen adsorbed in the microporous coordination polymer Cd(bpndc)(bpy). Journal of Low Temperature Physics, 159(1-2), 122-125. https://doi.org/10.1007/s10909-009-0084-8