Magnetic and dielectric properties of InFe2O4, InFeCuO4, and InGaCuO4

Kenji Yoshii, Naoshi Ikeda, Yuka Okajima, Yasuhiro Yoneda, Yoji Matsuo, Yoichi Horibe, Shigeo Mori

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Abstract

The magnetic and dielectric properties of InFe2O4, InFeCuO4, and InGaCuO4 have been investigated. All these materials are isostructural with RFe2O4 (R = Y, Ho-Lu), which shows ferroelectricity due to iron-valence ordering. InFe 2O4 exhibits ferrimagnetic ordering at Tc ∼ 242 K and a dielectric constant (ε) of ∼10000 at around room temperature. These properties resemble those of RFe2O4; the origins of the magnetic and dielectric phenomena are likely common in InFe2O4 and RFe2O4. From measurements of the other two materials, we found that both Tc and ε are decreased in the order of InFe2O4, InFeCuO 4, and InGaCuO4. This result strongly supports the previously reported explanation based on an electron transfer between the Fe-site ions for the corresponding rare-earth systems. Therefore, we propose that the dielectric properties of the oxides isostructural with AFe 2O4 are plausibly governed by electron transfer; this situation is different from that of ordinary ferroelectrics and dielectrics, in which the displacement of cations and anions is important. In addition, InFeCuO4 and InGaCuO4 exhibit large ε values (δ > ∼1500). In consideration of this property, we discuss the possible applications of these oxides.

Original languageEnglish
Pages (from-to)6493-6501
Number of pages9
JournalInorganic Chemistry
Volume47
Issue number14
DOIs
Publication statusPublished - Jul 21 2008

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Yoshii, K., Ikeda, N., Okajima, Y., Yoneda, Y., Matsuo, Y., Horibe, Y., & Mori, S. (2008). Magnetic and dielectric properties of InFe2O4, InFeCuO4, and InGaCuO4. Inorganic Chemistry, 47(14), 6493-6501. https://doi.org/10.1021/ic702365k