Mössbauer spectrum of high-pressure synthesized ilmenite-type FeGeO3

Tatsuo Fujii, D. Nakatsuka, Makoto Nakanishi, J. Takada, Takashi Yoshino

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Ilmenite-type FeGeO3 was prepared by high-pressure synthesis technique using a Kawai-type multi-anvil apparatus at 23.5 GPa and 500 °C. The effects of post annealing on the high-pressure synthesized samples were investigated by XRD analysis, Mössbauer spectroscopy and SQUID-magnetization measurements. The subsequent annealing after the high-pressure synthesis was effective to improve the crystallinity and increased the crystallite size of the ilmenite-type FeGeO3. The room temperature Mössbauer spectrum was composed of sharp paramagnetic doublets assigned to Fe2+. The well-crystallized ilmenite-type FeGeO3 showed typical antiferromagnetic behavior with the Néel temperature of 79 K, while the as-prepared sample without annealing demonstrated the superparamagnetic characteristics with larger magnetization.

Original languageEnglish
Pages (from-to)275-280
Number of pages6
JournalHyperfine Interactions
Volume226
Issue number1-3
DOIs
Publication statusPublished - 2014

Fingerprint

ilmenite
Annealing
annealing
Magnetization
magnetization
SQUIDs
synthesis
Crystallite size
anvils
crystallinity
Spectroscopy
Temperature
room temperature
spectroscopy
temperature

Keywords

  • Antiferromagnetism
  • High-pressure synthesis
  • Mössbauer spectroscopy

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Nuclear and High Energy Physics
  • Atomic and Molecular Physics, and Optics
  • Physical and Theoretical Chemistry

Cite this

Mössbauer spectrum of high-pressure synthesized ilmenite-type FeGeO3 . / Fujii, Tatsuo; Nakatsuka, D.; Nakanishi, Makoto; Takada, J.; Yoshino, Takashi.

In: Hyperfine Interactions, Vol. 226, No. 1-3, 2014, p. 275-280.

Research output: Contribution to journalArticle

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AU - Yoshino, Takashi

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