Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS

Yoshihiro Kubozono, T. Urakawa, Y. Yoshida, H. Maeda, Hiroyuki Ishida, Y. Furukawa, K. Yamada, S. Kashino

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Abstract

Rb K-edge EXAFS has been studied for K2RbC60 at 21 and 39 K and for KRb2C60 at 10 and 27 K. It is shown that the Rb+ ions in K2RbC60 occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb+ ions are off-centered. It is also found that the Rb+ ions in KRb2C60 occupy the octahedral and two tetrahedral sites.

Original languageEnglish
Pages (from-to)19-24
Number of pages6
JournalChemical Physics Letters
Volume255
Issue number1-3
Publication statusPublished - Jun 7 1996

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Kubozono, Y., Urakawa, T., Yoshida, Y., Maeda, H., Ishida, H., Furukawa, Y., Yamada, K., & Kashino, S. (1996). Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS. Chemical Physics Letters, 255(1-3), 19-24.