Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS

Yoshihiro Kubozono, T. Urakawa, Y. Yoshida, H. Maeda, Hiroyuki Ishida, Y. Furukawa, K. Yamada, S. Kashino

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Abstract

Rb K-edge EXAFS has been studied for K2RbC60 at 21 and 39 K and for KRb2C60 at 10 and 27 K. It is shown that the Rb+ ions in K2RbC60 occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb+ ions are off-centered. It is also found that the Rb+ ions in KRb2C60 occupy the octahedral and two tetrahedral sites.

Original languageEnglish
Pages (from-to)19-24
Number of pages6
JournalChemical Physics Letters
Volume255
Issue number1-3
Publication statusPublished - Jun 7 1996

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Kubozono, Y., Urakawa, T., Yoshida, Y., Maeda, H., Ishida, H., Furukawa, Y., ... Kashino, S. (1996). Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS. Chemical Physics Letters, 255(1-3), 19-24.

Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS. / Kubozono, Yoshihiro; Urakawa, T.; Yoshida, Y.; Maeda, H.; Ishida, Hiroyuki; Furukawa, Y.; Yamada, K.; Kashino, S.

In: Chemical Physics Letters, Vol. 255, No. 1-3, 07.06.1996, p. 19-24.

Research output: Contribution to journalArticle

Kubozono, Y, Urakawa, T, Yoshida, Y, Maeda, H, Ishida, H, Furukawa, Y, Yamada, K & Kashino, S 1996, 'Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS', Chemical Physics Letters, vol. 255, no. 1-3, pp. 19-24.
Kubozono, Yoshihiro ; Urakawa, T. ; Yoshida, Y. ; Maeda, H. ; Ishida, Hiroyuki ; Furukawa, Y. ; Yamada, K. ; Kashino, S. / Local structures around the Rb+ ion in K2RbC60 and KRB2C60 studied by Rb K-edge EXAFS. In: Chemical Physics Letters. 1996 ; Vol. 255, No. 1-3. pp. 19-24.
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AU - Maeda, H.

AU - Ishida, Hiroyuki

AU - Furukawa, Y.

AU - Yamada, K.

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