Lithium ion conductivity of Nd-doped (Li, La)TiO3 ceramics

Takashi Teranishi; Michihiro Yamamoto; Hidetaka Hayashi; Akira Kishimoto

doi:10.1016/j.ssi.2013.04.014

Lithium ion conductivity of Nd-doped (Li, La)TiO₃ ceramics

Takashi Teranishi, Michihiro Yamamoto, Hidetaka Hayashi, Akira Kishimoto

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Lithium (Li) ion conductivities of Nd-doped (Li, La)TiO₃ (LLNT) ceramics are evaluated as a function of Nd-loading. The bulk ion conductivity, σ_dc, improves for the specimen with ∼ 0.75 mol% Nd. The conductivity of the 0.5 mol% Nd-loaded LLNT is σ_dc = 1.26 × 10^{- 3} S cm^{- 1} at room temperature. It is the highest conductivity measured, and is 1.33 times higher than that of the non-doped ceramic. The enhancement of the Li ion conductivity with Nd-doping in the LLNTs is attributed to an increase in the volume fraction of the A-site disordered cubic phase.

Original language	English
Pages (from-to)	18-21
Number of pages	4
Journal	Solid State Ionics
Volume	243
DOIs	https://doi.org/10.1016/j.ssi.2013.04.014
Publication status	Published - 2013

Keywords

Complex conductivity
LLTO
Li ion conductor
Universal dielectric response

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Lithium ion conductivity of Nd-doped (Li, La)TiO3 ceramics",

abstract = "Lithium (Li) ion conductivities of Nd-doped (Li, La)TiO3 (LLNT) ceramics are evaluated as a function of Nd-loading. The bulk ion conductivity, σdc, improves for the specimen with ∼ 0.75 mol% Nd. The conductivity of the 0.5 mol% Nd-loaded LLNT is σdc = 1.26 × 10- 3 S cm- 1 at room temperature. It is the highest conductivity measured, and is 1.33 times higher than that of the non-doped ceramic. The enhancement of the Li ion conductivity with Nd-doping in the LLNTs is attributed to an increase in the volume fraction of the A-site disordered cubic phase.",

keywords = "Complex conductivity, LLTO, Li ion conductor, Universal dielectric response",

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AU - Teranishi, Takashi

AU - Yamamoto, Michihiro

AU - Hayashi, Hidetaka

AU - Kishimoto, Akira

PY - 2013

Y1 - 2013

N2 - Lithium (Li) ion conductivities of Nd-doped (Li, La)TiO3 (LLNT) ceramics are evaluated as a function of Nd-loading. The bulk ion conductivity, σdc, improves for the specimen with ∼ 0.75 mol% Nd. The conductivity of the 0.5 mol% Nd-loaded LLNT is σdc = 1.26 × 10- 3 S cm- 1 at room temperature. It is the highest conductivity measured, and is 1.33 times higher than that of the non-doped ceramic. The enhancement of the Li ion conductivity with Nd-doping in the LLNTs is attributed to an increase in the volume fraction of the A-site disordered cubic phase.

AB - Lithium (Li) ion conductivities of Nd-doped (Li, La)TiO3 (LLNT) ceramics are evaluated as a function of Nd-loading. The bulk ion conductivity, σdc, improves for the specimen with ∼ 0.75 mol% Nd. The conductivity of the 0.5 mol% Nd-loaded LLNT is σdc = 1.26 × 10- 3 S cm- 1 at room temperature. It is the highest conductivity measured, and is 1.33 times higher than that of the non-doped ceramic. The enhancement of the Li ion conductivity with Nd-doping in the LLNTs is attributed to an increase in the volume fraction of the A-site disordered cubic phase.

KW - Complex conductivity

KW - LLTO

KW - Li ion conductor

KW - Universal dielectric response

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